首页> 外国专利> MOLDED METAL-FIXED BED CATALYST, PRODUCTION OF ACTIVATED METAL-FIXED BED CATALYST AND UTILIZATION OF CATALYST FOR EXECUTION OF HYDROGENATION, AMINATION TYPE HYDROGENATION, DEHYDROGENATION AND HYDROCRCKING

MOLDED METAL-FIXED BED CATALYST, PRODUCTION OF ACTIVATED METAL-FIXED BED CATALYST AND UTILIZATION OF CATALYST FOR EXECUTION OF HYDROGENATION, AMINATION TYPE HYDROGENATION, DEHYDROGENATION AND HYDROCRCKING

机译:模制金属固定床催化剂,活性金属固定床催化剂的生产和用于加氢,胺化加氢,脱氢和加氢的催化剂的利用

摘要

PROBLEM TO BE SOLVED: To obtain a catalyst capable of advantageously performing the hydrogenation, dehydrogenation and hydrocracking of an organic and inorganic body by forming the catalyst only from a catalytic alloy and specifying total pore volume or the like in a molded metal-fixed bed catalyst containing a catalytic metal, an alloy component capable of eluting and if necessary, a co-catalyst. SOLUTION: In the metal-fixed bed catalyst, the catalyst is formed only from the catalytic alloy, attains 0.1-0.6 ml/g total pore volume and a part of an outside layer 0.1-2.0 mm thick from the surface is activated by the elusion of the alloy component capable being completely or partially eluted. And as the preferable catalyst component, nickel, cobalt, copper or iron and as the alloy component capable of eluting, aluminum, zinc or silicon is used. And the weight ratio of the catalyst metal and the alloy component capable of being eluted is setted to (30:70) to (70:30). Further s the co-catalyst, =15 wt.% element, such as chromium, iron, cobalt, tungsten, molybdenum, titanium per the weight of the catalytic alloy is added.
机译:要解决的问题:通过仅由催化合金形成催化剂并指定模制金属固定床催化剂中的总孔体积等来获得能够有利地进行有机和无机体的氢化,脱氢和加氢裂化的催化剂。含有催化金属,能够洗脱的合金组分以及必要时助催化剂。解决方案:在金属固定床催化剂中,该催化剂仅由催化合金形成,总孔体积达到0.1-0.6 ml / g,并且表面被厚度为0.1-2.0 mm的外层部分活化能够完全或部分洗脱的合金成分。并且作为优选的催化剂组分,使用镍,钴,铜或铁,并且作为能够洗脱的合金组分,使用铝,锌或硅。并且将能够洗脱的催化剂金属和合金组分的重量比设定为(30:70)至(70:30)。另外,加入每重量催化合金重量≤15重量%的助催化剂,例如铬,铁,钴,钨,钼,钛。

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