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shikurohekishirushikurohekisan derivative

机译:四黑平四六平山德里

摘要

NEW MATERIAL:A compound shown by formula I (R1 and R2 are 1-7C straight- chain alkyl; (n) is 2-7; group shown by formula IV is cyclohexane ring of trans- configuration). USE:An electro-optical display material. The liquid crystal compound having high nematic phase-isotropic liquid phase transition temperature, low anisotropy ( n) of refractive index of liquid crystal material to be packed into a cell, and excellent solubility in widely used nematic mixed liquid crystal, is useful for a material of liquid crystal display cell having excellent high-temperature driving characteristics and sight characteristics. PREPARATION:A compound shown by formula II is made to react with a compound shown by formula III in a toluene solvent in the presence of a base such as pyridine as a catalyst, the reaction mixture is mixed with 9% hydrochloric acid, extracted, washed with water, dried, then the solvent is distilled away under reduced pressure and the reaction product is recrystallized from an alcoholic solvent such as ethanol and purified to give a compound shown by formula I.
机译:新材料:式I所示的化合物(R 1和R 2为1-7C直链烷基;(n)为2-7;式IV所示的基团为反式构型的环己烷环)。用途:一种电光显示材料。具有高向列相-各向同性液晶相转变温度,要填充到单元中的液晶材料的折射率的各向异性(n)低和在广泛使用的向列混合液晶中优异的溶解性的液晶化合物对于材料是有用的。具有优异的高温驱动特性和视觉特性的液晶显示单元的制造方法。制备:使式Ⅱ所示的化合物与式Ⅲ所示的化合物在甲苯溶剂中,在碱如吡啶的存在下与甲苯反应,将反应混合物与9%盐酸混合,萃取,洗涤用水干燥,然后减压蒸馏除去溶剂,并将反应产物从醇溶剂如乙醇中重结晶并纯化,得到式I所示的化合物。

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