首页> 外国专利> 135- -246- 135-trissubstituted-catecholylmethyl-246- trialkylbenzene macrobicycles and their use for ion sensors

135- -246- 135-trissubstituted-catecholylmethyl-246- trialkylbenzene macrobicycles and their use for ion sensors

机译:135- -246- 135-三取代-邻苯二甲酰基甲基-246-三烷基苯大自行车及其在离子传感器中的用途

摘要

PURPOSE: Provided are a 1,3,5-tris(substituted catecholyl methyl)-2,4,6-trialkyl benzene compound with a cage structure, which can sense ammonium ions with excellent sensitivity and selectivity, and an ion sensor using the compound. CONSTITUTION: The 1,3,5-tris(substituted catecholyl methyl)-2,4,6-trialkyl benzene compound with the cage structure is represented by the formula 1, wherein R1, R2, and R3 are independently selected from the group consisting of hydrogen or C1-C10 alkyl, C1-C10 alkylthio, C1-C10 alkyloxy, C1-C10 alkylamine, C1-C10 alkylester, halogen, nitro, and amine. And the ion sensor is an ion selective electrode containing 0.5-5wt% of the 1,3,5-tris(substituted catecholyl methyl)-2,4,6-trialkyl benzene compound, 10-70wt% of a polymer support, and 10-70wt% of a plasticizer.
机译:用途:提供一种具有笼型结构的1,3,5-三(取代的邻苯二甲酰基甲基)-2,4,6-三烷基苯化合物,该化合物能够以优异的灵敏度和选择性检测铵离子,以及使用该化合物的离子传感器。组成:具有笼型结构的1,3,5-三(取代的邻苯二甲酰基甲基)-2,4,6-三烷基苯化合物由式1表示,其中R1,R2和R3独立地选自下组:氢或C 1 -C 10烷基,C 1 -C 10烷硫基,C 1 -C 10烷氧基,C 1 -C 10烷基胺,C 1 -C 10烷基酯,卤素,硝基和胺。并且离子传感器是离子选择电极,其包含0.5-5wt%的1,3,5-三(取代的儿茶酚基甲基)-2,4,6-三烷基苯化合物,10-70wt%的聚合物载体和10 -70wt%的增塑剂。

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