首页> 外国专利> DEVELOPMENT OF POLYMER SURFACE MODIFICATION BY HYDROGEN ION ASSISTED REACTION

DEVELOPMENT OF POLYMER SURFACE MODIFICATION BY HYDROGEN ION ASSISTED REACTION

机译:氢离子辅助反应改性聚合物表面的研究进展

摘要

The present invention provides a polymeric surface treatment method for converting the surface than layer by surface treatment of the polymer by hydrogen ion assisted reaction (Ion Assist Reaction) with a hydrophilic functional group, while damage to the CH or CHO bond present in the polymer surface to hydrogen ion beam surface by injecting the reactive gas is oxygen in a new way to make a new chemical bond on the surface species and lower layers. Compared with the case of surface-treated by using the conventional argon or other ion for hydrogen ion beam is a long period of time when not only a hydrophilic group formed on the surface of the surface is lower (or higher 100Å) even has formed a hydrophilic functional group was decreased contact angle hayeoteul especially stored in the water store it also was maintained a hydrophilic functional group formed on the surface of the lower layer as the hydrophilic functional group of the road surface to the PC and PET or the like formed in CHO case hayeoteul exposed in the air after a long period of time has elapsed measuring recovery of contact angle is less than 15 degrees as It was maintained. The hydrogen ion-assisted reaction method may be applied to such processing of the polyethylene membrane is used as the osmotic pressure of the electrolytic solution of a portable battery, separation became easier the movement of the electrolyte through the disadvantage of the pores of the polymeric osmotic pressure through the hydrogen-ion secondary Reaction rate the improved mechanical strength increased concerns when used for a long time than what was possible to solve the problems facing the membrane and change only the surface hydrophilic.
机译:本发明提供了一种聚合物表面处理方法,该方法用于通过具有亲水性官能团的氢离子辅助反应(离子辅助反应)对聚合物进行表面处理,同时破坏聚合物表面中存在的CH或CHO键,从而将表面转化为层表面。通过注入反应性气体向氢离子束表面注入氧气的新方法是在表面物质和下层上形成新的化学键。与使用常规氩气或其他离子进行氢离子束表面处理的情况相比,当不仅在表面形成的亲水基团较低(甚至更高)时甚至形成了亲水基团时,时间较长。亲水性官能团的接触角减小,尤其是在贮水器中储存时,也保持了在下层表面上形成的亲水性官能团,如在CHO中形成的PC和PET等道路表面的亲水性官能团长期暴露在空气中的哈耶特尔(Hayeoteul)的情况,保持接触角小于15度,恢复原状。氢离子辅助反应方法可以应用于聚乙烯膜的这种处理,因为便携式电池的电解液的渗透压高,分离变得容易使电解质通过聚合物渗透孔的缺点而移动。氢离子二次反应速率产生的压力提高,提高了机械强度,长时间使用比解决膜所面临的问题和仅改变表面亲水性的可能性高。

著录项

  • 公开/公告号KR100345289B1

    专利类型

  • 公开/公告日2002-07-25

    原文格式PDF

  • 申请/专利权人 한국과학기술연구원;

    申请/专利号KR19990039876

  • 发明设计人 조정;고석근;

    申请日1999-09-16

  • 分类号C08J7/00;

  • 国家 KR

  • 入库时间 2022-08-22 00:29:36

相似文献

  • 专利
  • 外文文献
  • 中文文献
获取专利

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号