jiasechiren chemical compound and its production mannered null expression which possess crown

摘要

PROBLEM TO BE SOLVED: To obtain the subject new compound having crown ether structure, high in ion transfer ability, capable of solid phase polymerization, and useful as a raw material for functional materials such as electroconductive materials, electrode materials, nonlinear optical materials, photosensitive materials and semiconductor crystals. ;SOLUTION: This new compound is shown by the formula CH₃-(CH₂)_k-C≡C- C≡C-(CH₂)_m-CO-¹E [(k) and (m) are each 1-12; E¹ is a structure of the formula ((n) is 1-4)], e.g. CH₃-(CH₂)₁₁-C≡C-C≡C-(CH₂)₈-COOH. This new compound of the above formula is obtained by reaction of a 1,3-alkadiynecarboxylic acid compound of the formula CH₃-(CH₂)_k-C≡C-C≡C-(CH₂)_m-COX (X is hydroxyl or a halogen) with an azacrown compound of the formula H-E¹ pref. at 1.1-1.2 mol per mol of the 1,3-alkadiynecarboxylic acid compound in an aprotic solvent (e.g. methylene chloride, an ether compound) in an inert gas atmosphere such as argon or nitrogen under normal pressures pref. at 25-40°C under agitation.;COPYRIGHT: (C)1999,JPO