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Optical active amino acid ester, reacting with the optical active amino acids which are displayed with the production mannered null
Optical active amino acid ester, reacting with the optical active amino acids which are displayed with the production mannered null
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机译:光学活性氨基酸酯,与光学活性氨基酸反应,以生产方式无效显示
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摘要
PROBLEM TO BE SOLVED: To efficiently obtain an optically active alcohol having high optical purity by carrying out optical resolution of amino acid esters comprising optically active amino acids and racemic alcohols and then hydrolyzing the resultant optically active aminoacid esters. ;SOLUTION: (C) Aminoacid esters synthesized by reacting (A) racemic alcohols with (B) optically active amino acids are subjected to diastereomer resolution to afford (D) the objective optically active amino acid esters. Further, the component D is hydrolyzed to provide the objective optically active alcohols important as raw materials for medicines and agrochemicals. The component A includes alkyl secondary alcohols such as methylethyl alcohol or aralkyl alcohols such as α-phenylethyl alcohol. The component B includes preferably natural type L-α-amino acids. Thereby, an optically active alcohol having high optical purity can readily be produced from racemic alcohol and the recovered optically active amino acid can be recycled.;COPYRIGHT: (C)1998,JPO
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