Increasing the catalytic activity and n/iso-selectivity for hydroformylation of olefin, comprises carrying out catalytic carbon to carbon bond formation reaction in polar or apolar solvent in presence of chiral and achiral phosphites

摘要

Method for increasing the catalytic activity and the n/iso-selectivity for the hydroformylation of olefins with transition metal-phosphite-complex-catalysts in homogeneous systems, comprises carrying out a catalytic C-C bond formation reaction in a polar or apolar single phase solvent mixture in the presence of chiral and achiral phosphites and diphosphites with subgroup element at 120-250[deg]C, where the amount of transition metal/phosphite-ratio in the complex catalyst is 1:0.5-1:10.