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Catalytic hydrogenation of sugar to sugar alcohol, using increasing reaction temperature and/or addition of monocarboxylic acid to maintain catalyst activity

机译:使用升高的反应温度和/或添加一元羧酸以保持催化剂活性,将糖催化氢化为糖醇

摘要

Preferably, the initial hydrogenation temperature is from 0 to 110{C and hydrogenation is conducted with simultaneous gradual heating at 0 to 5{C/min to achieve an increase of 20 to 100{C and a final hydrogenation temperature of from 60 to 200{C. The monocarboxylic acid is preferably formic acid, acetic acid, propionic acid or benzoic acid. The catalyst may also be washed with an alkali to regain the activity of the catalyst.
机译:优选地,初始氢化温度为0至110℃,并且以0至5℃/ min的同时逐步加热进行氢化,以实现20至100℃的升高,最终氢化温度为60至200℃。 C。一元羧酸优选为甲酸,乙酸,丙酸或苯甲酸。催化剂也可以用碱洗涤以恢复催化剂的活性。

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