Pesticide compositions based on Derivatives of 3 - piridilo, Seeds and Pest control methods and Protection of growing plants that use Derivatives of 3 - piridilo, processes for their Preparation and use as Pesticide Synergistic mixtures that the active principle.

摘要

Procedures for obtaining compounds (1) and the use of the compounds (1) or (2) and the compositions that include methods to combat pests, Pest Control and seed use and Derivatives of 3 - piridilo.Claim 1: Pesticide compositions, characterized in that it comprises (a) 3 - piridilo Derivatives of the formula (1) where X is Oxygen or Sulfur; R1 and R2 are independently of one another, The Hydrogen, halogen, alkyl, cyano, Nitro, haloalquilo - C1 - 6, 6 - C1 - C2, alquenilo - 6, haloalq Uenilo - C2 - 6, 6 - alquinilo C2, haloalquinilo - C2 - C3 - 6 - 6, cycloalkyl, halocicloalquilo - 6Cicloalquenilo - 6, 6 - halocicloalquenilo C3 alkyl, cycloalkyl - C1 - C3 - 6 - 6, Ori, Sri, S (= OR) ri (S = o) 2ri, nrirj, C (= o) sirizrj3z ORI (Z is 0 to 3), or phenyl Ring or a heteroaromu00e1tico of 5 to 6 Members, which can contain 1 to 4 heteroatoms selected from Oxygen, nitrogen and sulfur, or an Partially saturated or unsaturated Heterocyclic Illo with 3 to 7 members,It can contain 1 to 3 heteroatoms selected from Oxygen, nitrogen and sulfur, and carbon Atoms in the phenyl Ring or Heterocyclic heteroaromu00e1tico or be substituted with 1 to 3 groups are selected from Halogen, amino, cyano, Nitro Sri Ori, RI, and RI, RJ meant; An, each independently Hydrogen, alkyl - C1 - 6, 6 - haloalquilo C1, C2 alquenilo - 6Haloalquenilo - C2 - 6, 6 - alquinilo C2, haloalquinilo - C2 - C3 - 6 - 6, cycloalkyl, halocicloalquilo cicloalquenilo - 6, - 6, - halocicloalquenilo haloalcoxi C1 C3 - 6 - 6, c1-4 alkoxy alkyl C1 - 6, Alquiltio c1-4 alkyl C1 - 6, alquilsulfinil c1-4 alkyl C1 - 6, alquilsulfonil c1-4 alkyl haloalcoxi C1 C1 - 6 - 4 - alkyl haloalquiltio C1 C1 - 6 - 4 - 6 - alkoxy alkyl C1, c1-4 alkyl carbonyl - C1 - 6C1-4 alkyl amino alkyl dialkyl C1 C1 - 6 - 4 - amino alkyl cicloalquil C1 - C3 - 6 - 6, 6 - C1 alkyl, phenyl alkyl or alkyl of C1 - 6, 6 - C1, which is substituted with 1 to 3 cyano groups; R3 is Hydrogen, halogen or C1 - 6 alkyl; R4 is Hydrogen or alkyl of C1 - 6; R5 and R6 are each independently, d The other Hydrogen, halogen, alkyl, cyano, or C1 - 6; R7 is alkyl - C1 - C2 - 6 - 6, alquenilo,Alquinilo - C2 - C3 - 6 - 6, cycloalkyl, cicloalquenilo haloalquilo C1 - C3 - 6, - 6, - 6 haloalquinilo haloalquenilo C2, C2 - C3 - halocicloalquilo 6, 6, 6 halocicloalquenilo C3 -, or - C (= g) ra, - C (= ora, - C (g) (g) = - C (= nrarb, Nora) RB, cicloaiquil C1 - C3 alkyl - 6 - 6; g is o or s; ra, RB, each independently The other, halogeno, cyano, Nitro, alkyl - C1 - 6, 6 - haloalquilo C1, C2 alquenilo - 6Haloalquenilo - C2 - 6, 6 - alquinilo C2, haloalquinilo - C2 - C3 - 6 - 6, cycloalkyl, halocicloalquilo cicloalquenilo - 6, - 6, - 6 halocicloalquenilo, ork, SRK, S (S = o) (OR = RK, 2rk (= o, S) 2nrkrm) - C (= o) RK, ork - C (= o) - C (= o) - C (= nrkrm, RM, nork) - C (= (g) - (Z nrmrn NRK, sirkzrm3z is 0 to 3), or mean, RA, RB, Independently of one another, or a heteroaromu00e1tico phenyl Ring of 5 to 6 members,It can contain 1 to 4 heteroatoms selected from Oxygen, nitrogen and sulfur, or a partially saturated or unsaturated Heterocyclic Ring of 4 to 7, which can contain 1 to 3 heteroatoms selected from Oxygen, nitrogen and sulfur, and carbon Atoms in the Faith In the Nile or heteroaromu00e1tico Heterocyclic Ring or be substituted with 1 to 5 halogens; rk, RMMean RN, each independently Hydrogen, alkyl - C1 - 6, haloalquilo - C1 - C2 alquenilo - 6, - 6, - 6 alquinilo haloalquenilo C2, C2 - 6, 6 - haloalquinilo C2, C3 halocicloalquilo cycloalkyl - 6, - 6, - 6 cicloalquenilo halocicloalquenilo, - 6, and R7 is phenyl or a Heterocyclic Ring. Sewer or partially unsaturated 3 to 7 members,It can contain 1 to 3 heteroatoms selected from Oxygen, Sulphur and Nitrogen or a Ring System heteroaromu00e1tico of 5 to 6 members, which can contain 1 to 4 heteroatoms selected from Oxygen, nitrogen and sulfur, the phenyl Ring or Heterocyclic ring is heteroaromu00e1tico Are linked via a carbon Atom and the phenyl ring.Heterocyclic Ring or Ring heteroaromu00e1tico may be linked through - c1-4 alkyl, phenyl or heteroaromu00e1tico Ring or Heterocyclic Ring may be Condensed with a selected Ring between phenyl and Heterocyclic Ring partially unsaturated or saturated, aromatic Attic of 5 to 6 members, which can contain 1 to 3 heteroatoms selected from Oxygen,NITROGEN and sulfur, while groups R7 replaced or not, and the Hydrogen Atoms in these groups be replaced wholly or in part by any combination of selected groups of RC, RC represents halogeno, cyano, Nitro Regardless, C1 -, alkyl - haloalquilo - C1 - 6 6 Alquenilo - C2, C2 haloalquenilo - 6, - 6, - 6 haloalquinilo alquinilo C2, C2 - C3 - 6 - 6, cycloalkyl,Halocicloalquilo cicloalquenilo - 6, - 6, - 6 halocicloalquenilo, ork, SRK, S (= o) (OR = RK, S) 2rk, nrkrm RM, N (ORK), S (= o) 2nrkrm, - C (= o) - C (= o RK ork,) - C (= O) - C (= nrkrm, nork) - nrkc (= RM, RM, N (g) - (ORK) c = g) Rm, N (C (= RK (g) = (g)] [c] - RM, nrkc (= g) ORM, N (ORK) - C (= g) ORM, - C (= g) NRK nrmrn nrkso2rm sirkzrm3z -, -, (Z e S 0 to 3) or RC represents a phenyl ring, independently, or heteroaromu00e1tico of 5 to 6 members,It can contain 1 to 4 heteroatoms selected from Oxygen, nitrogen and sulfur, or a partially saturated or unsaturated Heterocyclic Ring of 4 to 7, which can contain 1 to 3 heteroatoms selected from Oxygen, nitrogen and sulfur, and carbon Atoms in the Faith In the Nile or heteroaromu00e1tico Heterocyclic Ring or be substituted with 1 to 5 halogens; rk, RMMean RN, each independently Hydrogen, alkyl - C1 - 6, haloalquilo - C1 - C2 alquenilo - 6, - 6, - 6 alquinilo haloalquenilo C2, C2 - 6, 6 - haloalquinilo C2, C3 halocicloalquilo cycloalkyl - 6, - 6, - 6 cicloalquenilo halocicloalquenilo, - 6, X is 0.Or 1; and is 0 OR 1; or Diastereomers, enantiomers or salts thereof and / or comprising (a) derivatives of 3 - piridilo 2 where the formula variables and indices have the meanings described above for compounds (1) with the exception of compounds where X, y are zero; R4 is Hydrogen - or a c1-4 alkyl; R1, R2, mean, each independently Hydrogen, halogeno, cyano,C1-4 alkyl -, - haloalquilo c1-4 alkoxy -, c1-4, Alquiltio - C1 - 4 - 4 - alquilsulfinilo C1, C1 alquilsulfonilo - - 4 - - 4 haloalquiltio C1, C1 haloalquilsulfinilo - - 4 - haloalquilsulfonilo c1-4, R5, R6 and R3 is Hydrogen or the Diastereomers, enantiomers or salts thereof; and (b) support agronomically ACE Ptable.