New ru00c9nio complexes with pyrazole or tris (1 - pirazolil) methane and its application as a catalyst of partial oxidation in mild conditions of ethane to acetic acid and acetaldeu00cddo and cyclohexane, the cycle hexanol and cyclohexane, the cycle hexanol and C

摘要

The invenu00c7u00c3o refers to new ru00c9nio complexes with pyrazole or tris (1 - pirazolil) methane, arrangements (1) to (4), and the use of those compounds and complexes relacionu00c1veis as catalysts (I) partial oxidation of ethane to acetic acid, (II) the partial oxidation of ethane to acetaldehyde and (III) partial oxidation of cyclohexane to peroxidativa cycle - hexanol and cyclohexanone.All the processes carried out in conditions with high yield and selectivity and smooth. The invenu00c7u00c3o also relates to advantageous use of microwaves in the synthesis of these complexes.