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2-oxabicyclo3.3.0octane compounds, process for producing the same, optical resolver, method of separating diastereomer mixture, and method of optically resolving alcohol
2-oxabicyclo3.3.0octane compounds, process for producing the same, optical resolver, method of separating diastereomer mixture, and method of optically resolving alcohol
2-Oxabicyclo[3.3.0]octane compounds represented by the following formula (1) (compound (1)); an optical resolver comprising at least one of the compounds (1); a process for producing the compounds (1) which comprises reacting a compound (2) or compound (3) with an alcohol (5) in the presence of an acid catalyst; a method of separating a diastereomer mixture of a compound (1); and a method of optically resolving an alcohol with the optical resolver.; [In the formulae, R1 to R10 each represents hydrogen atom, etc.; R11 represents an alkyl group, etc.; R12 represents a hydrocarbon group, etc.; R13 represents a hydrocarbon group, etc.; and A represents acetyl group, etc.]
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机译:由下式(1)表示的2-氧双环[3.3.0]辛烷化合物(化合物(1));一种光学分解器,其包含至少一种化合物(1);化合物(1)的制造方法,其包括在酸催化剂的存在下使化合物(2)或化合物(3)与醇(5)反应。分离化合物(1)的非对映异构体混合物的方法;以及用光学分解器光学拆分醇的方法。 化学>[式中,R 1 Sup>至R 10 Sup>分别表示氢原子等。 R 11 Sup>表示烷基等。 R 12 Sup>表示烃基等; R 13 Sup>表示烃基等。并且A表示乙酰基等。]
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