首页> 外国专利> ORGANIC-INORGANIC COMPOSITE OF NANO-TUBE TRANSCRIBED FROM (1R,2R)-DIPHENYL-ETHYLENE DIAMIDE AS TEMPLATE, NANOTUBE METAL OXIDES OBTAINED FROM ORGANIC-INORGANIC COMPOSITE AND FABRICATION PROCESS THEREOF

ORGANIC-INORGANIC COMPOSITE OF NANO-TUBE TRANSCRIBED FROM (1R,2R)-DIPHENYL-ETHYLENE DIAMIDE AS TEMPLATE, NANOTUBE METAL OXIDES OBTAINED FROM ORGANIC-INORGANIC COMPOSITE AND FABRICATION PROCESS THEREOF

机译:以(1R,2R)-二亚乙基-乙二胺为模板制备的纳米管的有机-无机复合物,由有机-无机复合物制得的纳米管金属氧化物及其制备方法

摘要

A method for preparing a nano-sized organic-inorganic composite, a nano-sized organic-inorganic composite prepared by the method, a method for preparing a metal oxide by using the composite, and a metal oxide prepared by the method are provided to control the final shape of macromolecular structured nanotubes stably irrespective of the change of pH and to enhance yield remarkably. A method for preparing a nano-sized organic-inorganic composite comprises reacting (1R, 2R)-diphenylethylenediamide represented by the formula 1 with an organic solvent or a mixture solvent of an organic solvent and water to induce an organic gel; and adding an inorganic precursor and water to carry out the sol-gel reaction by using the organic gel as a template, wherein R is a C1-C20 alkyl group, a C1-C20 alkenyl group, an amine group substituted with a C1-C20 alkyl, group, an aliphatic ammonium group substituted with a C1-C20 alkyl, group, an aromatic ammonium group substituted with a C1-C20 alkyl, group, or their mixture.
机译:提供用于控制纳米级有机-无机复合物的方法,通过该方法制备的纳米级有机-无机复合物,通过使用该复合物制备金属氧化物的方法以及通过该方法制备的金属氧化物。大分子结构的纳米管的最终形状稳定,与pH的变化无关,并显着提高了产率。一种制备纳米级有机-无机复合物的方法,该方法包括使式(1)表示的(1R,2R)-二苯基乙二酰胺与有机溶剂或有机溶剂与水的混合溶剂反应,以产生有机凝胶。然后,以有机凝胶为模板,添加无机前体与水进行溶胶-凝胶反应,其中,R为碳原子数为1〜20的烷基,碳原子数为1〜20的烯基,被碳原子数为1〜20的取代的胺基。烷基,被C1-C20烷基取代的脂族铵基,被C1-C20烷基取代的芳族铵基或它们的混合物。

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