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IMMOBILIZED LEWIS ACID CATALYSTS COATED WITH IONIC LIQUIDS AND USE THEREOF

机译:离子液体涂覆的固定化路易斯酸催化剂及其用途

摘要

The invention provides a novel immobilized Lewis acid catalyst which exhibits high catalytic activity in an aqueous solution and which permits recovery and reuse or long-term continuous use. The invention relates to an immobilized Lewis acid catalyst comprising a solid substance and a Lewis acid supported on the surface of the solid substance by chemical bonding, wherein the surface of the solid substance and the peripheries of the Lewis acid are coated with an ionic liquid, more specifically, an immobilized Lewis acid catalyst comprising a solid substance such as silica gel or an organic polymer and a Lewis acid stable even in water which is supported on the surface of the solid substance by chemical bonding, wherein the surface of the solid substance and the peripheries of the Lewis acid are completely or partially coated with a hydrophobic ionic liquid; a process for the production of the catalyst; use thereof; and a process for the preparation of compounds with the catalyst.
机译:本发明提供了新颖的固定化路易斯酸催化剂,其在水溶液中表现出高催化活性,并且允许回收和再利用或长期连续使用。本发明涉及一种固定化的路易斯酸催化剂,其包含固体物质和通过化学键合负载在固体物质表面上的路易斯酸,其中固体物质的表面和路易斯酸的外围被离子液体涂覆,更具体地,一种固定的路易斯酸催化剂,其包含诸如硅胶或有机聚合物的固体物质和甚至在水中稳定的路易斯酸,该路易斯酸通过化学键合被支撑在固体物质的表面上,其中路易斯酸的周围全部或部分被疏水性离子液体覆盖。催化剂的生产方法;使用;以及用催化剂制备化合物的方法。

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