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Synthesis of zeolite crystals and formation of carbon nanostructures in patterned structures

机译:沸石晶体的合成和图案结构中碳纳米结构的形成

摘要

A method is provided for incorporating zeolite crystals in patterned structures, the zeolite crystals having pores (channels) with an orientation which is defined by the topology of the zeolite crystal type and the geometry of the patterned structure, resulting in pores parallel with the length axis of the patterned structures. The patterned structures may be vias (vertical contacts) and trenches (horizontal lines) in a semiconductor substrate. These zeolite crystals can advantageously be used for dense and aligned nanocarbon growth or in other words growth of carbon nanostructures such as carbon nanotubes (CNT) within the pores of the zeolite structure. The growth of CNT is achieved within the porous structure of the zeolite crystals whereby the pores can be defined as confined spaces (channels) in nanometer dimensions acting as a micro-reactor for CNT growth. A method for growing carbon nanostructures within zeolite crystals is also provided, by adding, after creation of the zeolite crystals, a novel compound within the porous structure of the zeolite crystals whereby said novel compound is acting as a carbon source to create the carbon nanostructures. The improved growth method gives a significantly higher carbon density (yield) compared to state of the art techniques.
机译:提供了一种将沸石晶体结合到图案化结构中的方法,该沸石晶体具有孔(通道)的取向由沸石晶体类型的拓扑结构和图案化结构的几何形状限定,从而导致孔平行于长度轴的图案结构。图案化的结构可以是半导体衬底中的通孔(垂直接触)和沟槽(水平线)。这些沸石晶体可有利地用于致密且排列的纳米碳生长,或者换句话说,用于在沸石结构的孔内生长碳纳米结构,例如碳纳米管(CNT)。 CNT的生长是在沸石晶体的多孔结构内实现的,从而可以将孔定义为纳米尺寸的受限空间(通道),用作CNT生长的微反应器。还提供了一种在沸石晶体内生长碳纳米结构的方法,该方法是在产生沸石晶体后,在沸石晶体的多孔结构内添加新型化合物,其中所述新型化合物充当碳源以产生碳纳米结构。与现有技术相比,改进的生长方法可显着提高碳密度(产量)。

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