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METHOD OF PRODUCING NON-CHLORINE NPK COMPOUND FERTILISERS

机译:非氯氮磷钾复合肥的生产方法

摘要

FIELD: chemistry.;SUBSTANCE: method involves neutralisation of an acidic phosphorus-containing solution with an alkaline potassium-containing reagent at the first step and then adding sulphuric acid and neutralisation with ammonia at the second step, granulation and drying the end product. Nitric acid and ammonium nitrate are added when neutralising the acidic phosphorus-containing solution at the first step. The alkaline potassium-containing reagent and ammonium nitrate are added to the acidic phosphorus-containing solution while maintaining the required ratio of nutrient components in the end product. Nitric acid is added in an amount which provides pH 2-5 at the first step. The pH value at the second neutralisation step is kept at 4-6. The acidic phosphorus-containing solution used is phosphoric acid or a nitric-phosphate solution which is a product of decomposition of phosphate material with nitric acid with subsequent extraction of potassium in form of a tetrahydrate of calcium nitrate.;EFFECT: method enables to vary the ratio of nutrient substances in the product in a sufficiently wide range and increase strength of granules of the end product and improve its application properties.;4 cl, 4 ex
机译:领域:化学;方法:该方法包括在第一步中用碱性含钾试剂中和酸性含磷溶液,然后在第二步中加入硫酸和氨中和,制粒并干燥最终产物。在第一步中和酸性含磷溶液时,要添加硝酸和硝酸铵。将碱性含钾试剂和硝酸铵添加到酸性含磷溶液中,同时保持最终产品中营养成分的所需比例。硝酸的添加量应使第一步的pH值为2-5。第二中和步骤的pH值保持在4-6。所用的酸性含磷溶液是磷酸或硝酸磷酸盐溶液,该溶液是磷酸盐材料与硝酸分解,随后以硝酸钙四水合物形式提取钾的产物。产品中营养物质的比例应在足够宽的范围内,并增加最终产品颗粒的强度并改善其应用性能。; 4 cl,4 ex

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