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PROCESS FOR PRODUCING BLENDS MADE OF POLYLACTIDES (PLAS) AND OF THERMOPLASTIC POLYURETHANES (TPUS)

机译:生产聚乳酸(PLAS)和热塑性塑料(TPUS)制成的共混物的过程

摘要

Blends made of thermoplastic polyurethanes (TPUs) and of polylactides (PLAs) are produced viaA) reaction of at least one thermoplastic polyurethane with at least one diisocyanate or one diisocyanate prepolymer which has at least two isocyanate groups, or a mixture thereof, in the melt, with reduction of the molar mass of the thermoplastic polyurethane and with formation of a thermoplastic polyurethane having an excess of isocyanate end groups,B) introduction of at least one polylactide into the melt of the stage A) product, and reaction of the stage A) product with the polylactide at a temperature below 190° C.,C) cooling of the resultant blend,where no polyols are used in stages A) to C).
机译:热塑性聚氨酯(TPU)和聚丙交酯(PLA)制成的混合物是通过 A)至少一种热塑性聚氨酯与至少一种二异氰酸酯或一种至少具有二异氰酸酯预聚物的反应熔融物中的两个异氰酸酯基团或它们的混合物,同时降低了热塑性聚氨酯的摩尔质量并形成了具有过量异氰酸酯端基的热塑性聚氨酯, B)将至少一种聚丙交酯引入阶段A)产物的熔体中,并使阶段A)产物与聚丙交酯在低于190°C的温度下反应, < ListItem id =“ ul0001-0003” number =“ 0000”> C)冷却所得混合物,其中在步骤A)至C)中不使用多元醇。

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