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MANUFACTURING METHOD OF 1,3-BUTADIENE FROM 2,3-BUTANDIOL CAPABLE OF MANUFACTURING 1,3-BUTADIENE WITH EXCELLENT SELECTIVITY FROM 2,3-BUTANDIOLS WHICH IS A BIO-PLATFORM COMPOUND
MANUFACTURING METHOD OF 1,3-BUTADIENE FROM 2,3-BUTANDIOL CAPABLE OF MANUFACTURING 1,3-BUTADIENE WITH EXCELLENT SELECTIVITY FROM 2,3-BUTANDIOLS WHICH IS A BIO-PLATFORM COMPOUND
PURPOSE: A manufacturing method of 1,3-butadiene is provided to obtain 1,3-butadiene with high selectivity through a dehydration of 2,3-butandiol, and to able to manufacture 1,3-butadiene at low temperature with long term stability.;CONSTITUTION: A manufacturing method of 1,3-butadiene comprises a step of manufacturing 1,3-butadiene from 2,3-butanediol under the presence of a hydroxyapatite-alumina catalyst. The catalyst contains 5-40 weight% of alumina and 60-95 weight% of hydroxyapatite. The 1,3-butadiene is manufactured through a dehydration of the 2,3-butandiols. The dehydration is conducted under conditions of a reaction temperature of 320-430 C, a reaction pressure of 1-6 atm, and a liquid hour space velocity of 0.3-1.5 h^(-1).;COPYRIGHT KIPO 2013
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机译:目的:提供一种1,3-丁二烯的制备方法,以通过2,3-丁二醇的脱水获得高选择性的1,3-丁二烯,并能够在低温下长期稳定地制备1,3-丁二烯。组成:1,3-丁二烯的制造方法包括在羟基磷灰石-氧化铝催化剂存在下由2,3-丁二醇制造1,3-丁二烯的步骤。该催化剂含有5-40重量%的氧化铝和60-95重量%的羟基磷灰石。通过2,3-丁二醇的脱水来制造1,3-丁二烯。脱水在以下条件下进行:反应温度为320-430 C,反应压力为1-6 atm,液时空速为0.3-1.5 h ^(-1)。; COPYRIGHT KIPO 2013
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