Amide acid n - (1,3,4 Oxadiazoles - il - 2 - arilcarboxilico) and their use as herbicides

摘要

Amide acid n - (1,3,4 Oxadiazoles - il - 2) as agents arilcarboxu00edlico herbicides.Claim 1: amide acid n - (1,3,4 Oxadiazoles - il - 2 - arilcarboxu00edlico) of the formula (1) or its Salts, in which the substituents have the following Meanings: a Means or Cy N; R is Hydrogen, alkyl r1o C1 - 6, 6 - ch2r6 C1 alkyl, cycloalkyl, C3 haloalquilo C1 - 7 - 6, that Nile haloalquenilo C2 C2 - 6, - 6, - 6 haloalquinilo alquinilo C2, C2 - 6, OR1, nhr1, metoxicarbonilo,Ethoxycarbonyl, metoxicarbonilmetilo, etoxicarbonilmetilo, metilcarbonilo, trifluorometilcarbonilo, dimethylamino, Acetylamino, metilsulfenilo, metilsulfinilo, metilsulfonilo or heteroaryl substituted benzyl or phenyl, heterociclilo, respectively with s radical Group, halogen, Nitro, CIA No, I haloalquilo C1 C1 - 6 - 6, cycloalkyl C3 - 6 S (o) n - alkyl alkoxy C1 C1 - 6 - 6Haloalcoxi C1 C1 - 6, 6 - alkoxy alkyl c1-4, X is Halogen, Nitro, cyano, Formilo, Rhone, alkyl - 6 haloalquilo C1, C1 - C2 - alquenilo 6, 6, 6 alquinilo haloalquenilo C2, C2 - C3 - haloalquinilo 6, 6, 6 halocicloalquilo cycloalkyl C3, C3 - 6 - 6 - alkyl, cycloalkyl C3 C1 - C3 - 6, 6 - halocicloalquilo C1 - July 6, COR1, coor1, ocoor1, nr1coor1, C (o) n (2 nr1c (R1), or 2) n (R1), OC (o) n (R1) 2, C (OR) nr1or1, OR1,Ocor1, oso2r2, S (o) NR2, so2or1, so2n (R1) 2, nr1so2r2, nr1cor1, alkyl - C1 - 6 - S (o) NR2, alkyl - C1 - 6 - OR1, alkyl - 6 - ocor1 C1, C1 - 6 - oso2r2 alkyl, alkyl - C1 - 6 - co2r1, C1 - 6 - so2or1 alkyl, alkyl - C1 - 6 - 2 (R1, C1 alkyl) - 6 - so2n (R1) 2 - 6 - nr1cor1 C1 alkyl, alkyl C1 - 6 - nr1so2r2, nr1r2, P (o) (OR5 ch2p) 2 (o) (OR5) 2 C1 - 6 - heteroaryl alkyl, alkyl C1 - 6 - heterociclilo,While the last two mentioned remains respectively replaced with s remains Halogen, alkyl haloalquilo C1 C1 - 6 - 6, S (o) n - alkyl alkoxy C1 C1 - 6, - 6, - 6 and haloalcoxi C1 with the heterociclilo n oxo groups and means; Hydrogen, halogen, Nitro, cyano, Rhone, rent C1 - 6, haloalqui The C1 - C2 - alquenilo 6, 6, 6 alquinilo haloalquenilo C2, C2 - 6 - 6 haloalquinilo cycloalkyl, C2, C3 - 6Cicloalquenilo C3 - 6 - 6, halocicloalquilo C3 alkyl, cycloalkyl C1 - C3 - 6 - 6, halocicloalquilo C1 C3 alkyl - 6 - 6, COR1, coor1, ocoor1, nr1coor1, C (o) n (2 nr1c (R1), or (2) n, (R1) or oC (n) R1) 2, CO (nor1) R1, nr1so2r2, nr1cor1, OR1, oso2r2, S (o) NR2, so2or1 so2n (R1, C1 - alkyl) 2, 6 - S (o) NR2, C1 6... - alkyl, alkyl - 6 - ocor1 C1, C1 - 6 - oso2r2 alkyl, alkyl - 6 - co2r1 C1, C1 - 6 - (alkyl, alkyl C1 - 6 - so2or1,Alkyl C1 - 6 - (2 - alkyl R1), C1 (R1) so2n 6 - 2, 6 - nr1cor1 C1 alkyl, alkyl C1 - 6 - nr1so2r2 (R1), n 2, P (o) (OR5 ch2p (2), or (2) OR5), alkyl C1 - 6 - phenyl, alkyl C1 - 6 - 6 - C1 - heteroaryl alkyl, phenyl or heteroaryl heterociclilo, heterociclilo, being the last 6 remains respectively replaced with s Rad Icales Group, halogen, Nitro, cyano, C1 - 6 alkyl, cycloalkyl haloalquilo C1 - C3 - 6 6S (o) n - alkyl alkoxy C1 C1 - 6, - 6, - 6 haloalcoxi C1, C1 - 6 - alkoxy alkyl and cianometilo C1 - 4 oxo groups and Carrying the heterociclilo N; Z means Halogen alkyl, cyano, or C1, C1 - alkoxy - 6, 6, 6 haloalquilo C1, alquenilo haloalquenilo C2 C2 - 6, - 6, - 6 alquinilo C2, C2 haloalquinilo cycloalkyl - 6 C3 - 6 - 6, halocicloalquilo C3 alkyl, cycloalkyl C1 - C3 - 6 - 6, 6 - halocicloalquilo C1 C3 alkyl - 6COR1, coor1, ocoor1, nr1coor1, C (o) n (2 nr1c (R1), or 2) n (R1), OC (o) n (R1) 2, C (OR) nr1or1, oso2r2, S (o) NR2, so2or1, so2n (R1) 2, nr1so2r2, nr1cor1, alkyl C1 - 6 - S (o) NR2, alkyl alkyl OR1 - C1 - 6, 6 - ocor1 C1, C1 - 6 - oso2r2 alkyl, alkyl - 6 - co2r1 C1, C1 - 6 - so2or1 alkyl, alkyl C1 - 6 - 2 (R1, C1 alkyl) - 6 - so2n (R1) 2 Alkyl alkyl - 6 - nr1cor1 C1, C1 - 6 - nr1so2r2 (R1), n 2, P (o) (2 OR5), phenyl or heteroaryl, heterociclilo,While the last three remains respectively replaced with s radical Group, halogen, Nitro, cyano, C1 - 6 alkyl, cycloalkyl haloalquilo C1 - C3 - 6, 6, S (or C1) n - alkyl - or alkoxy C1 - 6, 6 - 6 haloalcoxi C1 and Carrying the heterociclilo n oxo groups, or z it can also mean Hydrogen In the event that represents the rest and S (o) NR2; r1 is Hydrogen, alkyl haloalquilo C1 C1 - 6 - 6Alquenilo haloalquenilo C2 C2 - 6, - 6, - 6 alquinilo C2, C2 C3 haloalquinilo cycloalkyl - 6, - 6, - 6 halocicloalquilo cicloalquenilo C3, C3 - 6, 6 - C1 - alkyl or cycloalkyl alkyl C1 - C3 - 6 - 6, 6 - C1 alkyl, phenyl, phenyl alkyl C1 6 - 6 - heteroaryl heteroaryl alkyl C1, C1, Heterocyclic alkyl -, 6 - heterocicl ILO, alkyl - or - C1 - 6 6 - C1 - heteroaryl alkyl, alkyl - or heterociclilo C1 - 6, - NR1 - heteroaryl,Alkyl C1 - 6 - NR1 - heterociclilo still remains above the last 21 replaced with Remnants of the group consisting of halogen, Nitro, cyano, Rhone, OR3, S (OR) NR4 (R3), n 2, nr3or3, cor3, ocor3, scor4, nr3cor3, nr3so2r4 co2r3 cosr4 (,,, R3) 2 - alkoxy - C1 and C2 - 4 and 6, with the alcoxicarbonilo Heterociclilo n groups oxo alkyl; R2 means C1 - 6 - 6, haloalquilo C1, C2 alquenilo - 6Haloalquenilo C2 - 6 - 6 alquinilo C2, C2, C3 haloalquinilo cycloalkyl - 6, - 6, - 6 halocicloalquilo cicloalquenilo C3, C3 - 6, 6 - C1 - alkyl or cycloalkyl alkyl C1 - C3 - 6 - 6, 6 - C1 alkyl phenyl, alkyl, phenyl heteroaryl alkyl, C1 - 6 C1 - 6 - heteroaryl alkyl heterociclilo, C1, C1 heterociclilo - 6 -, alkyl - 6 - Heteroaryl alkyl or - C1 -, 6 - or - alkyl heterociclilo C1 - 6, - NR1 - heteroaryl,Alkyl C1 - 6 - NR1 - heterociclilo still remains above the last 21 replaced with Remnants of the group consisting of halogen, Nitro, cyano, Rhone, OR3, S (OR) NR4 (R3), n 2, nr3or3, cor3, ocor3, scor4, nr3cor3, nr3so2r4 co2r3 cosr4 (,,, R3) 2 - alkoxy - C1 and C2 - 4 and 6, with the alcoxicarbonilo Heterociclilo n oxo groups; R3 is Hydrogen, alkyl alquenilo C1 - C2 - 6, 6, 6 alquinilo C2,C3-6 cycloalkyl alkyl or cycloalkyl C1 - C3 - 6 6 - 6 alkyl; R4 means C1, C2 or C2 alquinilo alquenilo - 6 - 6; R5 or R6 means means Methyl ethyl; acetoxy n-methylacetamide benzoyloxy acetamide, benzamide, n-methylbenzamide, metoxicarbonilo, Ethoxycarbonyl, Benzoyl metilcarbonilo, Piperi Dinilcarbonilo, morfolinilcarbonilo, trifluorometilcarbonilo, aminocarbonilo, metilaminocarbonilo,Dimetilaminocarbonilo alkoxy C1, C3 - 6 - 6, cycloalkyl or phenyl or heteroaryl, heterociclilo respectively replaced with s radical Group, methoxy, Methyl, Ethyl, trifluoromethyl and Halogen; n is 0, 1 or 2; S = 0, 1, 2 or 3; with the condition that X and Z Do not mean) Adapter The rest of the Group ultu00e1neamente chlorine, Fluorine, methoxy and methyl, and represents Hydrogen,(b) when X is not of Hydroxy and methoxy and Z represents represents Hydrogen, c) X is Chlorine or Bromine, and Z represents represents when Hydrogen and Fluorine, fluoride does not mean (d) x, and Z represents represents when Hydrogen and Bromine, and X or Z) do not represent Hydrogen, when repr You have f) R does not mean Nitrogen, trifluoromethyl, when X and Z represents represents acetoxy Methyl.