Energetic active composition, useful as an explosive, comprises a dihydroxylammonium salt or diammonium salt of 5,5'-bistetrazole-1,1'-diol, 5,5'-bistetrazole-1,2'-diol and/or 5,5'-bistetrazole-2,2'-diol

摘要

Energetic active composition comprises a dihydroxylammonium salt or diammonium salt of 5,5'-bistetrazole-1,1'-diol, 5,5'-bistetrazole-1,2'-diol, 5,5'-bistetrazole-2,2'-diol or a mixture of at least two of the above salts. Independent claims are included for: (1) the preparation of the dihydroxylammonium salt or diammonium salt of 5,5'-bistetrazole-1,1'-diol, 5,5'-bistetrazole-1,2'-diol, 5,5'-bistetrazole-2,2'-diol or a mixture of at least two of the above salts comprising (a) oxidizing 5,5'-bistetrazole to a mixture of 5,5'-bistetrazole-1,1'-diol, 5,5'-bistetrazole-1,2'-diol, 5,5'-bistetrazole-2,2'-diol or isomerizing diazido glyoxime to 5,5'-bistetrazole-1,1'-diol or 5,5'-bistetrazole-1,1'-diolate, (b) incubating the obtained reaction product with hydroxylamine, hydroxylammonium, ammonium ions or ammonia in aqueous solution and (c) separating the obtained precipitate; (2) a 5,5'-bistetrazole-1,2'-diol and 5,5'-bistetrazole-2,2'-diol; and (3) dihydroxylammonium salt or diammonium salt 5,5'-bistetrazole-1,2'-diol and 5,5'-bistetrazole-2,2'-diol.