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PROCESS FOR THE ACTIVATION OF THE C-H BOND OF ORGANIC COMPOUNDS AND A REACTIONS SYSTEM SERVING THE PROCESS

机译:活化有机化合物C-H键的方法和用于该方法的反应体系

摘要

A process is disclosed for the activation of the single covalent carbon-hydrogen bond of organic substrate compounds, and for the reaction, in particular deuteratrion thereof within mild reaction conditions, wherein said organic substrate compound is contacted with a Rutenium-complex, a phosphine, and a source of a hydrogen-substituent, thus the hydrogen of the C-H-bond is substituted by a hydrogen-substituent through the activation of the C-H bond by an in situ prepared Ru-phosphine catalyst. A reaction system for reacting of the C-H-bond is also disclosed. The process makes possible the selective reaction of the C-H-bond.
机译:公开了一种活化有机底物化合物的单个共价碳氢键,以及在温和的反应条件下进行反应,特别是其氘化的方法,其中所述有机底物化合物与钌络合物,膦,氢取代基的来源,因此,CH-键的氢通过原位制备的Ru-膦催化剂活化CH键而被氢取代基取代。还公开了用于使C-H键反应的反应系统。该方法使得C-H键的选择性反应成为可能。

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