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METHOD FOR PREPARING SILICON-MODIFIED ZSM-5 ZEOLITE CATALYST, CATALYST OBTAINED BY SAID METHOD, AND APPLICATION OF SAID CATALYST

机译:硅改性的ZSM-5沸石催化剂的制备方法,SAID法制得的催化剂及应用

摘要

The present invention provides a method for preparing a silicon-modified ZSM-5 zeolite catalyst, the method comprising the following steps: (1) dissolving a silicon source in a solvent, and obtaining a precursor solution; (2) adding the ZSM-5 zeolite to the precursor solution to form a suspension; (3) while stirring, raising the temperature and evaporating the suspension, then drying and baking the obtained solid; (4) extrusion molding or spray drying the baked solid powder. The present invention also provides a method for obtaining, by means of the described method, silicon-modified ZSM-5 zeolite catalyst and using the catalyst to prepare by methanol an alkene. By using the catalyst of the present invention, significantly improved C3 and C4 alkene selectivity can be obtained.
机译:本发明提供了一种制备硅改性的ZSM-5沸石催化剂的方法,该方法包括以下步骤:(1)将硅源溶解在溶剂中,得到前体溶液; (2)将ZSM-5沸石加入前体溶液中形成悬浮液; (3)在搅拌的同时,升高温度并使悬浮液蒸发,然后干燥并烘烤得到的固体; (4)挤压成型或将烘烤过的固体粉末喷雾干燥。本发明还提供一种通过所述方法获得硅改性的ZSM-5沸石催化剂并使用该催化剂通过甲醇制备烯烃的方法。通过使用本发明的催化剂,可以获得显着改善的C 3 和C 4 烯烃的选择性。

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