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FUNCTIONALIZED MULTI-BRANCHED POLYMERS, INCLUDING FUNCTIONALIZED POLYMERS, SYNTHESIZED BY ANION POLYMERIZATION, AND THEIR APPLICATION

机译:功能化多支化聚合物,包括功能化聚合物,通过阴离子聚合合成及其应用

摘要

1. A functionalized multi-branched polymer that contains the reaction product: (A) a crosslinking agent with a functional number of from 1 to 30, preferably from 5 to 20; and (B) a polymer synthesized by anionic polymerization, characterized in that the polymer synthesized by anionic polymerization has the formula (I) Li-QZT- (A-RRR), where Q is alkenyl aromatic monomers, conjugated dienes, or a mixture thereof, anionically polymerized by Li-Z, Z is a branched or unbranched hydrocarbon connecting group of 3 to 25 carbon atoms; T is an element selected from oxygen, sulfur and nitrogen; (A-RRR) is a protecting group, where A is an element selected from carbon (C) or silicon (Si), preferably silicon (Si), R, R, R are independently selected from hydrogen, alkyl groups, alkyl groups substituted with C A -C, C-Styoalkyl and C-C-dialkylamine group, an aryl group or an aryl group substituted with a C-C-alkyl, C-Styoalkyl and C-C-dialkylamine group, a cycloalkyl group of 5 to 12 carbon atoms, or a cycloalkyl group of 5 up to 12 carbon atoms substituted with a C -C alkyl, C-Styoalkyl and C-C dialkylamine group, m is 1 when T is oxygen or sulfur, and m is 2 when T is nitrogen, n is a number units of diene monomers, alkenyl aromatic monomers or any monomers in their anionically polymerized mixtures. 2. The functionalized multi-branched polymer according to claim 1, characterized in that it contains from 1 to 30 chains of the synthesized
机译:1.一种官能化的多支化聚合物,其包含反应产物:(A)官能度为1至30,优选5至20的交联剂;和(B)通过阴离子聚合合成的聚合物,其特征在于,通过阴离子聚合合成的聚合物具有式(I)的Li-QZT-(A-RRR),其中Q为烯基芳族单体,共轭二烯或其混合物。 ,由Li-Z阴离子聚合,Z为3至25个碳原子的支链或直链烃连接基团; T是选自氧,硫和氮的元素; (A-RRR)是保护基,其中A是选自碳(C)或硅(Si)的元素,优选地,硅(Si),R 1,R 2和R 3独立地选自氢,烷基,被取代的烷基具有CA -C,C-Styo烷基和CC-二烷基胺基,被CC-烷基,C-Styo烷基和CC-二烷基胺基取代的芳基或芳基,5至12个碳原子的环烷基或环烷基由5个至多12个碳原子取代的C-C烷基,C-Styo烷基和CC二烷基胺基的基团,当T为氧或硫时m为1,当T为氮时m为2单体,烯基芳族单体或它们的阴离子聚合混合物中的任何单体。 2.根据权利要求1的官能化的多支链聚合物,其特征在于它包含1至30个合成的链。

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