首页> 外国专利> PROCESS FOR PREPARING A CATALYST IMPLEMENTING AT LEAST ONE QUICK DRYING STEP AND AT LEAST ONE FLUIDIZED BED DRYING STEP AND USE THEREOF FOR THE FISCHER-TROPSCH SYNTHESIS

PROCESS FOR PREPARING A CATALYST IMPLEMENTING AT LEAST ONE QUICK DRYING STEP AND AT LEAST ONE FLUIDIZED BED DRYING STEP AND USE THEREOF FOR THE FISCHER-TROPSCH SYNTHESIS

机译:至少一次快速干燥步骤和至少一个流化床干燥步骤中制备催化剂的方法,并将其用于费-托合成

摘要

The present invention relates to a process for preparing a catalyst comprising an active phase comprising at least one Group VIII metal chosen from cobalt, nickel, ruthenium and iron, alone or as a mixture, and an oxide support, said process comprising at least one step of stabilizing said oxide support, consisting of a step of impregnating said oxide support, a step of fast drying, a step of calcining said impregnated and dried oxide support, said calcination being carried out in one or two steps, said stabilization step being followed at least once, the sequence of the following steps, a step of impregnating said stabilized oxide support, a step of drying said stabilized and impregnated oxide carrier operating in a fluidized bed, in the presence of a gas said support being subjected to a ramp for increasing the temperature between 0.5 and 5 ° C / min to reach a temperature of between 50 and 170 ° C, the residence time of said support, once the drying temperature has been reached, in said drying step being between 20 and 180 min, and a step of calcining said stabilized oxide support impregnated and dried.
机译:本发明涉及制备包含活性相的催化剂的方法,该活性相包含至少一种选自钴,镍,钌和铁的至少一种VIII族金属,单独或以混合物形式存在,所述方法包括至少一个步骤稳定所述氧化物载体的步骤,包括浸渍所述氧化物载体的步骤,快速干燥的步骤,煅烧所述浸渍和干燥的氧化物载体的步骤,所述煅烧分一两个步骤进行,所述稳定化步骤在至少一次,以下步骤的顺序:浸渍所述稳定化的氧化物载体的步骤,干燥在流化床中操作的所述稳定化和浸渍的氧化物载体的步骤,在存在气体的情况下,使所述载体经受用于增加的斜面在达到干燥温度后,以0.5至5℃/ min的温度达到50至170℃的温度,所述载体的停留时间为所述干燥步骤为20至180分钟,以及煅烧浸渍并干燥的所述稳定化氧化物载体的步骤。

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