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SYSTEM AND PROCESS FOR DETERMINING AND ANALYSING SURFACE PROPERTY PARAMETERS OF SUBSTANCE BASED ON KINETIC METHOD

机译:基于动力学方法的物质表面特性参数测定与分析系统及过程

摘要

A system and process for determining and analyzing surface property parameters of a substance based on kinetic method is provided. The system comprises a sample processing system and a detection system. The sample processing system includes a reactor (3), a collector for liquid to be tested (5), and a container for liquid to be tested (6). The detection system includes a detecting electrode (13), a concentration and activity operator, a kinetic data processor, a surface property operation module, and a result output module. The process comprises: having the substance to be tested to be treated with an electrolyte solution, measuring activity of liquid to be tested upon reaction at a pre-set time interval, and processing with the kinetic data processor and the surface property operation module, so as to obtain surface property parameters of the substance to be tested. The present invention adopts kinetic method of ion exchange to overcome the issues associated with long reaction equilibrium time, not easy to determine equilibrium and not easy to accurately determine the value of m. Five parameters of the substance surface property can be calculated with only intercept and gradient of the linear regression equation obtained from the kinetic data, and the total amount of surface charge can also be directly determined.
机译:提供了一种基于动力学方法确定和分析物质的表面特性参数的系统和过程。该系统包括样品处理系统和检测系统。样品处理系统包括反应器( 3 ),待测液体的收集器( 5 )和待测液体的容器( 6 < / B>)。该检测系统包括检测电极( 13 ),浓度和活性算子,动力学数据处理器,表面性质操作模块和结果输出模块。该过程包括:用电解质溶液处理待测物质,在预设的时间间隔测量反应后待测液体的活性,并用动力学数据处理器和表面性质操作模块进行处理,因此以获得待测物质的表面性能参数。本发明采用离子交换的动力学方法,克服了反应平衡时间长,不易确定平衡,不易准确确定m值的问题。仅从动力学数据获得的线性回归方程的截距和斜率就可以计算出物质表面性质的五个参数,并且还可以直接确定表面电荷的总量。

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