首页> 外国专利> Methods of production of polyalkylene terephthalate, production of an article molded article molded of polyalkylene terephthalate and polyalkylene terephthalate, polyethylene terephthalate, and article molded of polyethylene terephthalate (PET)

Methods of production of polyalkylene terephthalate, production of an article molded article molded of polyalkylene terephthalate and polyalkylene terephthalate, polyethylene terephthalate, and article molded of polyethylene terephthalate (PET)

机译:聚对苯二甲酸亚烷基酯的制造方法,由聚对苯二甲酸亚烷基酯和聚对苯二甲酸亚烷基酯模制的成型品,聚对苯二甲酸乙二醇酯,聚对苯二甲酸乙二醇酯(PET)成型的品的制造方法

摘要

The present invention provides a method of producing polyalkylene terephthalate, which comprises: introducing a prepolymer of polyalkylene terephthalate that is in a molten state comprising 70 mol% or more of ethylene terephthalate or 1,4-butylene terephthalate repeating units and having an intrinsic viscosity [] between 0.2 and 2 dl/g through a feed opening to a polymerization reactor; discharging the introduced prepolymer from holes of a perforated plate; and polymerizing the prepolymer under reduced pressure, while allowing the prepolymer to fall along the surface of a support that is open towards the outside at a temperature between the [crystalline melting point - 10 DEG C] of the prepolymer or higher and the [crystalline melting point + 30 DEG C] of the prepolymer or lower under the conditions represented by a formula S 1 /S 2 1, wherein S1 is the surface area of falling polyalkylene terephthalate, and S2 is the area where the support is in contact with polyalkylene terephthalate.
机译:本发明提供了一种生产聚对苯二甲酸亚烷基酯的方法,该方法包括:引入处于熔融状态的聚对苯二甲酸亚烷基酯的预聚物,该预聚物包含70摩尔%或更多的对苯二甲酸乙二酯或1,4-对苯二甲酸丁二酯重复单元并具有特性粘度[通过聚合反应器的进料口在0.2和2dl / g之间;从多孔板的孔中排出引入的预聚物;使该预聚物在减压下聚合,同时使该预聚物在预聚物的[结晶熔点-10℃]或更高与[结晶熔体]之间的温度下沿着向外部敞开的载体表面落下。在式S 1 / S 2> 1表示的条件下,预聚物的熔点为+ 30℃或更低;其中S1为下降的聚对苯二甲酸亚烷基二醇酯的表面积,S2为载体与聚亚烷基接触的面积对苯二甲酸酯。

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