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COMPLEX OF ORGANIC COMPOUND AND COPPER NANOPARTICLES, COMPLEX OF ORGANIC COMPOUND AND COPPER OXIDE (I) NANOPARTICLES, AND PROCESSES FOR PRODUCTION OF THE COMPLEXES
COMPLEX OF ORGANIC COMPOUND AND COPPER NANOPARTICLES, COMPLEX OF ORGANIC COMPOUND AND COPPER OXIDE (I) NANOPARTICLES, AND PROCESSES FOR PRODUCTION OF THE COMPLEXES
Provided is a composite including copper nanoparticles or copper(I) oxide nanoparticles and a thioether-containing organic compound represented by X(OCH2CHR1)nOCH2CH(OH)CH2SZ [X represents an alkyl group; R1 represents a hydrogen atom or a methyl group; n represents an integer of 2 to 100; R1 is independent between repeating units and may be the same or different; and Z represents an alkyl group, an allyl group, an aryl group, an arylalkyl group, -R2-OH, -R2-NHR3, or -R2-(COR4)m (where R2 represents a saturated hydrocarbon group; R3 represents a hydrogen atom, an acyl group, an alkoxycarbonyl group, or a benzyloxycarbonyl group; R4 represents a hydroxy group, an alkyl group, or an alkoxy group; and m represents 1 to 3)]. Provided is a method for producing a composite of an organic compound and copper nanoparticles or a composite of an organic compound and copper(I) oxide nanoparticles, the method including reducing a copper compound in the presence of a thioether-containing organic compound represented by the general formula (1) above.
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机译:提供一种复合物,其包含铜纳米粒子或氧化铜(I)纳米粒子和以X(OCH 2 CHR 1)n OCH 2 CH(OH)CH 2 SZ表示的含硫醚的有机化合物[X表示烷基; R1代表氢原子或甲基; n表示2〜100的整数。 R1在重复单元之间是独立的,可以相同或不同; Z代表烷基,烯丙基,芳基,芳烷基,-R2-OH,-R2-NHR3或-R2-(COR4)m(其中R2代表饱和烃基; R3代表氢原子,酰基,烷氧基羰基或苄氧基羰基; R 4表示羟基,烷基或烷氧基;并且m表示1-3)]。本发明提供一种有机化合物与铜纳米粒子的复合物或有机化合物与氧化铜(I)纳米粒子的复合物的制造方法,该方法包括在以所述化合物表示的含硫醚的有机化合物的存在下还原铜化合物。上述通式(1)。
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