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METHOD OF CATALYTIC GASIFICATION OF BIOMASS WITH OBTAINING GASEOUS FUELS

机译:含气态气体催化气化生物质的方法

摘要

FIELD: chemistry.;SUBSTANCE: invention relates to field of application of renewable sources of raw material - biomass. Claimed is method of catalytic gasification of biomass with obtaining gaseous fuels. Method includes milling biomass and its thermal processing in air medium at 600÷800°C and pressure 1.2-2.0 atm, catalytic thermal degradation of gaseous products in presence of transition metals, method differs by the fact that catalytic thermal degradation is realised at temperature 500÷550°C, weight ratio of catalyst and biomass is 0.01÷0.05 and air consumption 1.0÷2.5 m3 per 1 kg of biomass, and as catalyst is applied mixture of oxides of chrome and vanadium, applied on natural aluminosilicate in quantity 1÷20 wt % and 1÷5 wt % respectively, or as catalyst applied is mixture of oxides of molybdenum and manganese, applied on natural aluminosilicate in quantity 1÷10 wt % and 10÷30 wt % respectively, or as catalyst applied is mixture of cobalt and nickel oxides, applied on natural aluminosilicate in quantity 5÷25 wt % and 1÷40 wt % respectively.;EFFECT: increased output of flammable hydrocarbons, achievement of good efficiency of gasification.;6 tbl, 6 ex
机译:技术领域本发明涉及可再生原料-生物质的应用领域。要求保护的是获得气态燃料催化气化生物质的方法。方法包括在600÷800°C和1.2-2.0 atm的压力下在空气介质中研磨生物质及其热处理,在过渡金属存在下气态产物的催化热降解,方法的不同之处在于在温度500℃下实现催化热降解÷550°C,催化剂与生物质的重量比为0.01÷0.05,每1千克生物质空气消耗量为1.0÷2.5 m 3 ,并且作为催化剂,使用铬和钒的氧化物混合物在天然硅铝酸盐上的量分别为1÷20 wt%和1÷5 wt%,或者作为催化剂使用的是钼和锰的氧化物混合物,分别在数量上1÷10 wt%和10÷30 wt%的天然硅铝酸盐上施用,或作为催化剂使用的是钴和氧化镍的混合物,分别以5÷25 wt%和1÷40 wt%的量施加在天然铝硅酸盐上;效果:增加了可燃烃的产量,实现了良好的气化效率; 6 tbl ,6前

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