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METHOD FOR MANUFACTURING SOLID OXIDE FUEL CELL ANODE WITH HIGH STABILITY AND HIGH EFFICIENCY

机译:一种高稳定性,高效率的固体氧化物燃料电池阳极的制备方法

摘要

A nanostructured anode of solid oxide fuel cell with high stability and high efficiency and a method for manufacturing the same are revealed. This anode comprising a porous permeable metal substrate, a diffusion barrier layer and a nano-composite film is formed by atmospheric plasma spray. The nano-composite film includes a plurality of metal nanoparticles, a plurality of metal oxide nanoparticles, and a plurality of gas pores that are connected to form nano gas channels. The metal nanoparticles are connected to form a 3-dimensional network that conducts electrons, while the metal oxide nanoparticles are connected to form a 3-dimensional network that conducts oxygen ions. The network formed by metal oxide nanoparticles has certain strength to separate metal nanoparticles and prevent aggregation or agglomeration of the metal nanoparticles. Thus this anode can be applied to a solid oxide fuel cell operating in the intermediate temperatures (600˜800° C.) with high stability and high efficiency.
机译:公开了具有高稳定性和高效率的固体氧化物燃料电池的纳米结构阳极及其制造方法。通过大气等离子体喷涂形成包括多孔可渗透金属基底,扩散阻挡层和纳米复合膜的阳极。纳米复合膜包括多个金属纳米颗粒,多个金属氧化物纳米颗粒和多个气孔,它们连接形成纳米气体通道。连接金属纳米颗粒以形成传导电子的3维网络,而连接金属氧化物纳米颗粒以形成传导氧离子的3维网络。由金属氧化物纳米颗粒形成的网络具有一定的强度以分离金属纳米颗粒并防止金属纳米颗粒的聚集或附聚。因此,该阳极可以以高稳定性和高效率应用于在中间温度(600〜800℃)下操作的固体氧化物燃料电池。

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