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method for preparing copper containing hydrogenation catalyst and use of copper containing hydrogenation catalyst

机译:含铜氢化催化剂的制备方法及含铜氢化催化剂的用途

摘要

The present invention provides a method of preparing the copper-containing hydrogenation catalyst having high activity by liquid phase reduction without decreasing purity of the solvent and a method for efficiently producing an alcohol. The present invention provides the method of preparing the copper-containing hydrogenation catalyst, including reducing a molded precursor of the copper-containing hydrogenation catalyst by supplying hydrogen gas or a mixture of hydrogen gas with an inert gas at a temperature of 50 to 150°C in the presence of a solvent to obtain the copper-containing hydrogenation catalyst, wherein the reduction is conducted at an average reduction velocity of the copper-containing hydrogenation catalyst of not more than 3.0% by weight/hour. The present invention also provides the method of producing an alcohol, including preparing the copper-containing hydrogenation catalyst by the method of preparation, and subjecting a carboxylic acid or a carboxylic acid ester to catalytic reduction with hydrogen in the presence of the prepared copper-containing hydrogenation catalyst.
机译:本发明提供在不降低溶剂纯度的情况下通过液相还原制备具有高活性的含铜氢化催化剂的方法和有效制备醇的方法。本发明提供了一种制备含铜氢化催化剂的方法,该方法包括通过在50至150℃的温度下供应氢气或氢气与惰性气体的混合物来还原含铜氢化催化剂的模制前体。在溶剂的存在下获得含铜氢化催化剂,其中还原以不大于3.0重量%/小时的含铜氢化催化剂的平均还原速度进行。本发明还提供了一种制备醇的方法,包括通过该制备方法制备含铜氢化催化剂,以及在制备的含铜存在下用氢对羧酸或羧酸酯进行催化还原。加氢催化剂。

著录项

  • 公开/公告号BRPI0918567A2

    专利类型

  • 公开/公告日2016-02-10

    原文格式PDF

  • 申请/专利权人 KAO CORPORATION;

    申请/专利号BR2009PI18567

  • 发明设计人 SHOJI HASEGAMA;TORU SAKAMOTO;

    申请日2009-09-10

  • 分类号B01J23/80;B01J37/18;C07B61;C07C29/149;C07C31/125;

  • 国家 BR

  • 入库时间 2022-08-21 14:26:50

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