首页> 外国专利> 4-(5-hexylthiophene-2-o)-2,6-bis5-(selenophene-2-o)thiophene-2-opyridine, method for obtaining it and enzymatic electrode for detection of phenolic compounds in water solutions

4-(5-hexylthiophene-2-o)-2,6-bis5-(selenophene-2-o)thiophene-2-opyridine, method for obtaining it and enzymatic electrode for detection of phenolic compounds in water solutions

机译:4-(5-己基噻吩-2-o)-2,6-双[5-(硒吩-2-o)噻吩-2-o]吡啶,其制备方法和用于检测水溶液中酚类化合物的酶电极

摘要

the application concerns a new pyridine derivative which is a 4 - (5 - heksylotiofen - 2 -) - 2,6-bis [5 - (selenofen - 2 - thiophene - 2 -)] pyridine of formula 1, intended to sensorowych devices.process for the production of 4 - (5 - heksylotiofen - 2 -) - 2,6-bis [5 - (selenofen - 2 - thiophene - 2 -)] pyridine of formula 1, is that between 2,6 bis (5 - bromotiofen - 2 -) - 4 - (5 - heksylotiofen - 2 -) pyridine and 4,4,5,5 - tetramethyl - 2 - (selenofen - 2 -) - 1,3,2 - coupling reaction in the presence of dioksoborolanem is kat alizatora and aliquatu 336 and standing of potassium carbonate.the environment is a combination of reaction of toluene, water and ethanol in inertnej atmosphere.the application also relates to the enzymatic detection of phenolic compounds in aqueous solution, which contains an active layer in the form of lakazy zimmobilizowanej surface elektroprzewodzu0105cego film (p) obtained from material comprising 4 - (5 - heksylotiofen - 2 - ) - 2,6-bis [5 - (selenofen - 2 - thiophene - 2 -)] pyridine.
机译:本申请涉及一种新的吡啶衍生物,其是式1的4-(5-5-己基噻吩-2-)-2,6-双[5-(硒代苯酚-2-噻吩-2-)]吡啶,旨在用于传感装置。制备式1的4-(5-5-己基噻吩-2-)-2,6-双[5-(硒代苯酚-2-噻吩-2-))吡啶的方法是在2,6-双(5-在dioksoborolanem存在下,溴苯噻吩-2-)-4-(5-heksylotiofen-2-)吡啶和4,4,5,5-四甲基-2-(selenofen-2-)-1,3,2-偶联反应环境是由甲苯,水和乙醇在惰性气氛中反应而来的,该环境还涉及到水溶液中酚类化合物的酶促检测,该溶液中有一个活性层。从包含4-(5-heksylotiofen-2-)-2,6-bis [5-(selenof)的材料获得的lazy zimmobilizowanej表面elektroprzewodz cego薄膜(p)的形式en-2-噻吩-2-)]吡啶。

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