首页> 外国专利> - - Preparation method of organic-inorganic hybrid silica gel impregnated with silver nano-particles and the organic-inorganic hybrid silica gel impregnated with silver nano-particles thereby

- - Preparation method of organic-inorganic hybrid silica gel impregnated with silver nano-particles and the organic-inorganic hybrid silica gel impregnated with silver nano-particles thereby

机译:--浸渍有银纳米颗粒的有机-无机杂化硅胶的制备方法和由此浸渍的银-纳米颗粒的有机-无机杂化硅胶

摘要

The present invention relates to a method for preparing an organic-inorganic hybrid silica gel comprising the steps of: (1) preparing an organic-inorganic hybrid silica gel; And a step (step 2) of irradiating the organic-inorganic hybrid silica gel prepared in the step 1 with a radiation having an irradiation energy of 1 keV to 10 MeV after immersing the organic-inorganic hybrid silica gel in a solution containing the silver precursor, Organic-inorganic hybrid silica gel. In the method for producing an organic-inorganic hybrid silica gel impregnated with silver nanoparticles according to the present invention, silver nanoparticles reduced from a silver precursor solution by irradiating an electron beam are irradiated not only on the surface of the organic-inorganic hybrid silica gel, It can be impregnated as a whole. In addition to adsorbing organic iodine and gaseous iodine by introducing amines and thiol-based ligands known to be frequently used to remove carbon dioxide (CO 2 ), hydrogen (H 2 ) and inert gases, silver nanoparticles Iodine, iodine-related aerosols and iodine By adsorbing ions (I - ) at the same time, they have differentiation and superiority from other known adsorbents. Further, while the adsorbents are conventionally used once, the material prepared by the process of the present invention is an adsorbent that can be recycled several times.
机译:本发明涉及一种有机-无机杂化硅胶的制备方法,包括以下步骤:(1)制备有机-无机杂化硅胶;然后,在将有机无机杂化硅胶浸入含有银前驱体的溶液中之后,对步骤1中制得的有机无机杂化硅胶进行照射,照射能量为1keV〜10MeV。 ,有机-无机杂化硅胶。在根据本发明的浸渍有银纳米粒子的有机-无机杂化硅胶的制造方法中,通过照射电子束从银前体溶液中还原而得到的银纳米粒子不仅被照射在有机-无机杂化硅胶的表面上。 ,可以整体浸渍。除了通过引入胺和硫醇基配体来吸附有机碘和气态碘外,胺和硫醇基配体通常被用来去除二氧化碳(CO 2 ),氢(H 2 )惰性气体,银纳米颗粒碘,与碘有关的气溶胶和碘通过同时吸附离子(I -),它们与其他已知的吸附剂具有区别和优越性。此外,尽管吸附剂通常仅使用一次,但是通过本发明的方法制备的材料是可以循环使用几次的吸附剂。

著录项

  • 公开/公告号KR101653982B1

    专利类型

  • 公开/公告日2016-09-06

    原文格式PDF

  • 申请/专利权人 한국원자력연구원;

    申请/专利号KR20140148285

  • 发明设计人 임희정;최광순;

    申请日2014-10-29

  • 分类号C01B33/157;B82Y30;

  • 国家 KR

  • 入库时间 2022-08-21 14:11:59

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