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PLASMA-CHEMICAL METHOD OF PRODUCING CHALCOGENIDE GLASS OF As-S SYSTEM AND DEVICE THEREFOR

机译:生产as-s系统硫属玻璃的等离子体化学方法及其装置

摘要

FIELD: glass.;SUBSTANCE: invention relates to production of high-purity chalcogenide glass for producing optical elements, light guides and wide-gap semiconductor devices. Invention enables to avoid contamination of obtained chalcogenide glass due to partial decomposition of initial substances, as well as reduces amount of impurities, coming from materials equipment. Method of producing chalcogenide glass involves loading initial substances containing arsenic and sulphur, in flow plasma-chemical reactor, initiating interaction reaction of arsenic and sulphur high-frequency plasma discharge in conditions of nonequilibrium plasma at low pressure to form a charge chalcogenide glass and obtaining of chalcogenide glass. Initial substances used are elementary arsenic As and sulphur S, and inert gas is used as transport and plasma-forming gas. Obtaining of chalcogenide glass is performed by sealing reactor and its installation in swinging furnace, melting and homogenisation of glass-forming compounds and their cooling. Device comprises plasma-chemical reactor and pumping system.;EFFECT: reactor is made in form of a flow quartz tube, equipped with plasma-forming system and system of diagnostics, and system for feeding selected gas mixture comprises especially pure quartz reservoirs with loading quartz containers for solid-state arsenic and sulphur.;3 cl, 1 dwg, 2 tbl
机译:技术领域本发明涉及用于生产光学元件,光导和宽间隙半导体器件的高纯度硫属化物玻璃的生产。本发明能够避免由于原料物质的部分分解而污染所获得的硫属化物玻璃,并且减少了来自材料设备的杂质的量。硫属化物玻璃的制造方法包括在流式等离子体化学反应器中装载含砷和硫的初始物质,在非平衡等离子体的低压下引发砷和硫高频等离子体放电的相互作用反应以形成带电荷的硫属化物玻璃并获得硫属化物玻璃。所使用的初始物质是元素砷As和硫S,惰性气体用作传输气体和等离子体形成气体。硫族化物玻璃的获得是通过密封反应器并将其安装在回转炉中,玻璃形成化合物的熔融和均质化及其冷却来进行的。装置包括等离子化学反应器和泵送系统。效果:反应器以流动石英管的形式制成,配有等离子形成系统和诊断系统,供入所选混合气体的系统包括特别是装有石英的纯石英储层固态砷和硫的容器。; 3 cl,1 dwg,2 tbl

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