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Quadrupole mass spectrometer with quadrupole mass filter as a mass separator

机译:具有四极质量过滤器作为质量分离器的四极质谱仪

摘要

In a scan measurement in which a mass scan is repeated across a predetermined mass range, when a voltage is returned from a termination voltage of one scan to an initiation voltage for the next scan, an undershoot or other drawbacks occur to destabilize the voltage value. Therefore, an appropriate waiting time is required. Conventionally, this waiting time has been set to be constant regardless of the analysis conditions. On the other hand, in the quadrupole mass spectrometer according to the present invention, the mass difference ΔM between the scan termination mass and the scan initiation mass is computed based on the specified mass range, and a different settling time is set in accordance with this mass difference. When the mass difference ΔM is small and hence requires only a short voltage stabilization time, a relatively short settling time is set. This shortens the cycle period of the mass scan, which increases the temporal resolution.
机译:在其中在预定质量范围上重复进行质量扫描的扫描测量中,当电压从一个扫描的终止电压返回到下一次扫描的起始电压时,会出现下冲或其他缺陷,从而使电压值不稳定。因此,需要适当的等待时间。通常,不管分析条件如何,该等待时间都被设置为恒定。另一方面,在根据本发明的四极质谱仪中,基于指定的质量范围计算扫描终止质量与扫描起始质量之间的质量差ΔM,并据此设置不同的稳定时间。质量差异。当质量差ΔM较小并且因此仅需要短的电压稳定时间时,设置相对短的建立时间。这缩短了质量扫描的周期,从而提高了时间分辨率。

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