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SELECTIVE SEPARATION OF ELEMENTS OR COMMODITIES OF INTEREST IN AQUEOUS STREAMS

机译:水流中元素或商品的选择性分离

摘要

A process for selectively separating a metallic constituent from other metals and other materials accompanying the metallic constituent in a mixture is described. The process comprises the step of providing the mixture in an aqueous solution such that the metallic constituent forms a complex anion in the solution. One or more of the other metals forms a cation or a complex cation in the solution. Another step includes contacting the solution with one or more additives to form layered double hydroxide (LDH) material in situ such that the complex anion is intercalated within interlayers of the LDH material and wherein one or more of the other metals are incorporated into the LDH material's crystal structure or matrix. Another step involves the addition of an LDH to an aqueous solution. The process involves selectively recovering the metallic constituent from the interlayer of the LDH by subjecting the LDH to a recovery treatment step(s) and as required, methods to modify the LDH to facilitate metal separation and recovery or contaminant stabilisation.
机译:描述了一种用于将金属成分与混合物中伴随金属成分的其他金属和其他材料选择性分离的方法。该方法包括以下步骤:在水溶液中提供混合物,使得金属成分在溶液中形成配位阴离子。一种或多种其他金属在溶液中形成阳离子或络合阳离子。另一个步骤包括使溶液与一种或多种添加剂接触以原位形成层状双氢氧化物(LDH)材料,以使络合物阴离子插入LDH材料的中间层中,并且其中一种或多种其他金属被掺入LDH材料的晶体结构或基质。另一步骤涉及将LDH添加到水溶液中。该方法包括通过使LDH经历回收处理步骤来选择性地从LDH的中间层中回收金属成分,并且根据需要提供改性LDH以促进金属分离和回收或污染物稳定化的方法。

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