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METHOD FOR PRODUCING PERHALOGENATED HEXASILANE ANION AND METHOD FOR PRODUCING A CYCLIC SILANE COMPOUND

机译:制备高取代度己硅烷阴离子的方法和制备环状硅烷化合物的方法

摘要

The present invention relates to a process for the production of perhalogenated hexasilane anion by reacting halogenated monosilane in the presence of organosubstituted ammonium and/or phosphonium halide at temperatures in a range from 100 to 120° C., wherein no solvent is used, and a process for the production of a cyclic silane compound of the formula Si6R12, by reacting [X]2[Si6Cl14] with AlR3 in at least one organic solvent, wherein R is chlorine or methyl and X, the same or different, is a counter-cation and is preferably selected from organosubstituted ammonium, organosubstituted phosphonium, alkali metal ions and [(PEDETA)(H2SiCl)]+.
机译:本发明涉及通过在有机取代的铵和/或卤化phospho的存在下在100至120℃的温度下使卤代的甲硅烷反应的方法来生产全卤代的六硅烷阴离子的方法,其中不使用溶剂。 [X] 2 [Si 6]反应制备式Si 6 R 12 的环状硅烷化合物的方法在至少一种有机溶剂中具有AlR 3 Cl 14 ],其中R是氯或甲基,X相同或不同,X是抗衡阳离子并优选选自有机取代的铵,有机取代的,、碱金属离子和[(PEDETA)(H 2 SiCl)] +。

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