首页> 外国专利> - CATALYST SUITABLE FOR PRODUCTION OF AVIATION KEROSENE FROM BIOMASS FISCHER-TROPSCH SYNTHESIS OIL AND PREPARATION METHOD THEREFOR

- CATALYST SUITABLE FOR PRODUCTION OF AVIATION KEROSENE FROM BIOMASS FISCHER-TROPSCH SYNTHESIS OIL AND PREPARATION METHOD THEREFOR

机译:-适合于由生物质费-托合成油制备航空煤油的催化剂及其制备方法

摘要

A catalyst suitable for the production of aviation kerosene from biomass Fischer-Tropsch synthetic oil and a method for producing the same are disclosed. The weight percentages of various components in the catalyst are 20-50% amorphous aluminum-silicon, 5-20% aluminum oxide binder, 20-60% ZSM-22 molecular sieve modified with hydrothermal treatment, 0.5-5% nickel oxide, and molybdenum oxide 5-15%. First, H-ZSM-22 molecular sieve was obtained by carrying out NH4 + exchange treatment on K-ZSM-22 molecular sieve, and hydrothermal treatment was performed to obtain modified H-ZSM-22 molecular sieve And then mixed uniformly with the amorphous aluminum-silicon. Then, an aluminum oxide binder and a sesambana powder were added, mixed and kneaded, pulverized by clusters, formed by band extrusion, dried and roasted, Finally, the active metals Ni and Mo are loaded. The catalysts obtained from the present invention have high activity and high selectivity, increase the degree of isomerization of long-chain alkanes, lower the freezing point of a part of air kerosene, and improve the yield of air kerosene.
机译:公开了适用于由生物质费-托合成油生产航空煤油的催化剂及其生产方法。催化剂中各种组分的重量百分比为20-50%的非晶态铝硅,5-20%的氧化铝粘合剂,20-60%的经水热处理改性的ZSM-22分子筛,0.5-5%的氧化镍和钼氧化物5-15%。首先,对K-ZSM-22分子筛进行NH 4 +交换处理,得到H-ZSM-22分子筛,进行水热处理得到改性的H-ZSM-22分子筛,然后与无定形铝均匀混合。 -硅。然后,添加氧化铝粘合剂和芝麻糊粉,混合并捏合,通过团簇粉碎,通过带材挤出形成,干燥并焙烧,最后,装载活性金属Ni和Mo。由本发明获得的催化剂具有高活性和高选择性,增加了长链烷烃的异构化程度,降低了一部分煤油的冰点,并提高了煤油的收率。

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