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Perovskite oxide catalyst for oxygen evolution reactions

机译:用于氧释放反应的钙钛矿氧化物催化剂

摘要

A catalyst for an oxygen evolution reaction has a higher and longer-life catalytic activity than that of the conventional and expensive noble metal oxide catalysts, such as RuO2 and IrO2. An A-site ordered perovskite oxide catalyst (such as CaCu3Fe4O12 and CaMn3Mn4O12 etc.) as an oxygen evolution reaction catalyst is excellent in cost effectiveness. The catalyst has a high catalytic activity compared with a noble metal oxide catalyst, and a long repetition use life since it is extremely stable also under the oxidative reaction conditions. Use of the catalyst is expected to the important energy conversion reactions such as a charge reaction of a metal-air battery, an anode oxygen evolution reaction in the case of a direct water decomposition reaction by sunlight, etc.
机译:与传统昂贵的贵金属氧化物催化剂(如RuO 2 和IrO 2 )相比,用于析氧反应的催化剂具有更高的寿命和更长的寿命。一种A位有序钙钛矿氧化物催化剂(例如CaCu 3 Fe 4 O 12 和CaMn 3 Mn <作为氧析出反应催化剂的Sub> 4 O 12 等具有优异的成本效益。与贵金属氧化物催化剂相比,该催化剂具有高催化活性,并且由于其在氧化反应条件下也极其稳定,因此具有长的重复使用寿命。期望将催化剂用于重要的能量转化反应,例如金属-空气电池的充电反应,在通过阳光的直接水分解反应的情况下的阳极氧放出反应等。

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