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u- Cu-BASED CATALYST ITS PREPARATION PROCESS AND USE THEREOF

机译:u-Cu基催化剂的制备方法及其用途

摘要

The present invention relates to a Cu-based catalyst, a preparing method thereof, and a use of the Cu-based catalyst as a dehydrogenation catalyst in the preparation of a hydroxyketone compound such as acetoin. The Cu-based catalyst comprises copper, at least one auxiliary metal selected from a Group IIA metal, a Group VIII non-noble metal, a Group VIB metal, a Group VIIB metal, a Group IIB metal, and a lanthanide metal of a periodic table of elements, an alkali metal, and at least one ketone additive selected from ketones represented by formulas (II) R_1-C(=O)-CH(OH)-R_2 and (II′) R_1-C(=O)-CH(=O)-R_2. The Cu-based catalyst exhibits high acetoin selectivity as a dehydrogenation catalyst for preparing acetoin. In the equations (II, II′), each Group is defined as in the detailed description.
机译:本发明涉及一种铜基催化剂,其制备方法,以及该铜基催化剂作为脱氢催化剂在制备羟基酮化合物如丙酮中的用途。铜基催化剂包括铜,选自IIA族金属,VIII族非贵金属,VIB族金属,VIIB族金属,IIB族金属和周期性的镧系金属中的至少一种辅助金属。元素表,碱金属和至少一种选自式(II)R_1-C(= O)-CH(OH)-R_2和(II')R_1-C(= O)-表示的酮的酮添加剂CH(= O)-R_2。作为用于制备丙酮酸的脱氢催化剂,Cu基催化剂显示出较高的丙酮酸选择性。在等式(II,II')中,每个组如详细描述中所定义。

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