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METHOD FOR DECONTAMINATION OF WASTE WATER OF GOLD-MINING FACTORY

机译:一种金矿厂废水的去污方法

摘要

FIELD: chemistry.;SUBSTANCE: invention relates to methods of purifying waste water containing simple and complex cyanides, rhodanides, as well as arsenic and non-ferrous metals and can be used for decontaminating the liquid phase of tails of cyanide leaching of noble metals from ores, concentrates and man-made wastes. Object of the invention is to purify cyano-containing waste water from gold recovery factories from cyanide and rhodanide ions with achievement of their concentrations, meeting requirements for recycled water and water discharged to tailing dump of gold recovery factories, as well as reduced concentration of arsenic, copper and nickel due to the possibility of monitoring and controlling pH during the entire decontamination process. Task is achieved by the fact that, in the method of decontaminating effluents of a gold-mining factory, which includes treatment with ozone, according to the invention, neutralization is carried out by ozone supplied in the form of an ozone-oxygen mixture with ozone concentration of not less than 103 g/m3, and constant monitoring and regulation of pH value, which is not less than 11 units, is carried out by addition of lime milk with concentration of calcium oxide of 10 %. throughout the entire decontamination process. Implementation of the method of decontaminating effluents of a gold-mining factory with ozone supplied in the form of an ozone-oxygen mixture at constant monitoring and regulating a pH value of not less than 11 units, during the entire decontamination process, besides removing cyanide- and thiocyanate ions, enables to purify solutions from arsenic, copper and nickel.;EFFECT: technical result of the invention is a single-step complex purification of cyano-containing waste water from sodium cyanide and rhodanide ions to content that meets requirements for recycled and purified water, as well as reduced content of arsenic, copper and nickel.;1 cl
机译:发明领域本发明涉及净化包含简单和复杂的氰化物,罗丹酸盐以及砷和有色金属的废水的方法,并且可以用于净化从贵金属中浸出的氰化物尾矿的液相。矿石,精矿和人造废物。发明内容本发明的目的是从氰化物和罗丹酸根离子中达到其浓度,从循环水和排放到金回收工厂的尾矿堆中的水的要求,以及降低砷的浓度,从氰化物和罗丹酰胺离子中纯化金回收工厂中的含氰废水。 ,铜和镍,因为在整个净化过程中都可以监控pH值。通过以下事实来实现任务,即在根据本发明的对包括用臭氧处理的金矿工厂的废水进行净化的方法中,中和是通过以臭氧-氧气混合物形式提供的臭氧与臭氧进行中和的。浓度不低于103 g / m 3 ,并通过添加氧化钙浓度为10的石灰乳对pH值进行不小于11个单位的连续监测和调节%。在整个消毒过程中。在整个净化过程中,实施以不间断监测和调节pH值不少于11个单位的方式,以臭氧-氧气混合物形式供应的臭氧净化金矿工厂废水的方法,除了去除氰化物外,效果:本发明的技术结果是从氰化钠和罗丹酸根离子中一步纯化出含氰基的废水,使其含量达到可回收再利用的要求。纯净水,以及降低的砷,铜和镍含量。; 1 cl

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