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POLYMERIZABLE COMPOUND POLYMERIZABLE COMPOSITION POLYMER AND OPTICAL ANISTROPIC BODY
POLYMERIZABLE COMPOUND POLYMERIZABLE COMPOSITION POLYMER AND OPTICAL ANISTROPIC BODY
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机译:聚合性化合物聚合性聚合物和光学各向异性体
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摘要
The present invention is a polymerizable compound represented by formula (I); A polymerizable composition containing the polymerizable compound and a polymerization initiator; A polymer obtained by polymerizing the polymerizable compound or polymerizable composition; And it is an optically anisotropic body using the polymer as a constituent material. According to the present invention, a polymerizable compound and polymerization capable of obtaining an optical film which has a practical low melting point, has excellent solubility in a general-purpose solvent, can be manufactured at low cost, and is capable of constant polarization conversion in a wide wavelength range Sex compositions, polymers, and optically anisotropic materials are provided. [Wherein, Y 1 ∼ Y 8 is a chemical single bond, -O-, -OC (= O)-, -OC (= O) -O-, etc., G 1 , G 2 are carbon atoms of 1-20 Divalent aliphatic groups and the like, Z 1 and Z 2 are alkenyl groups having 2 to 10 carbon atoms which may be substituted with halogen atoms, and A X are represented by the following formula (II) (X represents a nitrogen atom, R a , R b represents a hydrogen atom, an aromatic hydrocarbon ring group having 1 to 20 carbon atoms, etc.), A y represents a hydrogen atom, a group represented by formula (II), etc. , A 1 is a trivalent aromatic group, A 2 , A 3 is a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms, A 4 , A 5 is a divalent aromatic group having 4 to 30 carbon atoms, Q, etc. 1 represents a hydrogen atom, a C1-C6 alkyl group, etc.]
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机译:本发明是式(I)表示的聚合性化合物。包含可聚合化合物和聚合引发剂的可聚合组合物;通过聚合可聚合化合物或可聚合组合物获得的聚合物;并且,是使用聚合物作为构成材料的光学各向异性体。根据本发明,能够得到实用上低的熔点,在通用溶剂中的溶解性优异,能够以低成本制造,并且能够恒定地进行偏振转换的光学膜的聚合性化合物和聚合。提供了宽的波长范围的性组合物,聚合物和光学各向异性材料。 [其中,Y 1 Sup>〜Y 8 Sup>是化学单键,-O-,-OC(= O)-,-OC(= O)-O-,等等,G 1 Sup>,G 2 Sup>是1-20个二价脂肪族基团的碳原子等,Z 1 Sup>和Z 2 Sup>是碳原子数2〜10的可被卤素原子取代的烯基,A X Sup>由下式(II)表示(X表示氮原子,R < Sup> a Sup>,R b Sup>代表氢原子,碳原子数为1至20的芳香烃环基等),A y Sup>代表氢原子,式(II)表示的基团等。A 1 Sup>是三价芳族基团,A 2 Sup>,A 3 Sup>是a具有3至30个碳原子的二价脂环族烃基,A 4 Sup>,A 5 Sup>是具有4至30个碳原子,Q等的二价芳族基团。 1 Sup>代表氢原子,C1-C6烷基等。]
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