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Comparative characterization of phenolic and other polar compounds in Spanish melon cultivars by using high-performance liquid chromatography coupled to electrospray ionization quadrupole-time of flight mass spectrometry

机译:高效液相色谱与电喷雾电离四极杆飞行时间质谱联用对西班牙瓜品种中酚类和其他极性化合物的比较表征

摘要

Melon (Cucumis melo L.), belonging to the Cucurbitaceae family, is a significant source of phytochemicals which provide human health benefits. High-performance liquid chromatography coupled to electrospray ionization mass spectrometry quadropole-time of flight (HPLC-ESIQTOF-MS) was used for the comprehensive characterization of 14 extracts from 3 Spanish varieties of melon (Galia, Cantaloupe, and Piel de Sapo). A total of 56 different compounds were tentatively identified, including: amino acids and derivatives, nucleosides, organic acids,udphenolic acids and derivatives, esters, flavonoids, lignans, and other polar compounds. Of these, 25 were tentatively characterized for the first time in C. melo varieties. Principalcomponent analysis (PCA) was applied to gain an overview of the distribution of the melon varieties and to clearly separate the different varieties. The result of the PCA for the negative mode was evaluated. The variables most decisive to discriminate among varieties included 12 of the metabolites tentatively identified.
机译:属于葫芦科的瓜(Cucumis melo L.)是提供人类健康益处的重要植物化学物质来源。高效液相色谱与电喷雾电离质谱联用四极杆飞行时间(HPLC-ESIQTOF-MS)用于全面表征3个西班牙甜瓜品种的14种提取物(Galia,Cantaloupe和Piel de Sapo)。初步鉴定出总共56种不同的化合物,包括:氨基酸和衍生物,核苷,有机酸,二酚酸和衍生物,酯,类黄酮,木脂素和其他极性化合物。其中,有25个首次在C. melo品种中得到初步鉴定。应用主成分分析(PCA)可以了解甜瓜品种的分布并清楚地区分不同品种。对负模式的PCA结果进行了评估。决定性地区分品种的变量包括初步鉴定出的12种代谢物。

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