首页> 外文OA文献 >Rheological properties of polymer melt between rapidly oscillating plates: An application of multiscale modeling
【2h】

Rheological properties of polymer melt between rapidly oscillating plates: An application of multiscale modeling

机译:快速振荡板之间聚合物熔体的流变特性:多尺度建模的应用

摘要

The behavior of supercooled polymer melt composed of short chains with 10 beads between rapidly oscillating plates is simulated by using a hybrid simulation of molecular dynamics and computational fluid dynamics. The flow profiles of polymer melt near an oscillating plate are quite different from those of Newtonian fluid. The viscous boundary layer of the melt is much thinner than that of the Newtonian fluid due to the shear thinning of the melt. Three different rheological regimes, i.e., the viscous fluid, viscoelastic liquid, and viscoelastic solid regimes, form over the oscillating plate according to the local Deborah numbers. The melt behaves as a viscous fluid when ωτR lsim 1, and the crossover between the liquid-like and solid-like regime takes place around ωτα sime 1 (where ω is the angular frequency of the plate, and τR and τα are the Rouse and α relaxation times, respectively).
机译:通过使用分子动力学和计算流体动力学的混合模拟,可以模拟由短链和10个小珠组成的过冷聚合物熔体在快速振荡板之间的行为。靠近振荡板的聚合物熔体的流动曲线与牛顿流体的流动曲线有很大不同。由于熔体的剪切稀化,熔体的粘性边界层比牛顿流体的边界层薄得多。根据当地的Deborah数,在振荡板上形成了三种不同的流变状态,即粘性流体,粘弹性液体和粘弹性固体状态。当ωτRlsim 1时,熔体表现为粘性流体,液体状态和固体状态之间的交叉发生在ωταsime 1附近(其中ω是板的角频率,而τR和τα是Rouse和α弛豫时间)。

著录项

  • 作者

    Yasuda S.; Yamamoto R.;

  • 作者单位
  • 年度 2009
  • 总页数
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类

相似文献

  • 外文文献
  • 中文文献
  • 专利

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号