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Three-dimensional simulations of transient response of PEM fuel cells

机译:PEM燃料电池瞬态响应的三维模拟

摘要

Transients have utmost importance in the lifetime and performance degradation of PEM fuel cells. Recent studies show that cyclic transients can induce hygro-thermal fatigue. In particular, the amount of water in the membrane varies significantly during transients, and determines the ionic conductivityudand the structural properties of the membrane. In this work, we present three-dimensional time-dependent simulations and analysis of the transport in PEM fuel cells. U-sections of anode and cathode serpentine flow channels, anode and cathode gas diffusion layers, and the membrane sandwiched between themudare modeled using incompressible Navier-Stokes equations in the gas flow channels, Maxwell-Stefan equations in the channels and gas diffusion layers, advection-diffusion-type equation for water transport in the membrane and Ohm’s law for ionic currents in the membrane and electric currents in gas diffusion electrodes. Transient responses to step changes in load, pressureudand the relative humidity of the cathode are obtained from simulations, which are conducted by means of a third party finite-element package, COMSOL.
机译:瞬态对PEM燃料电池的寿命和性能下降至关重要。最近的研究表明,周期性瞬变会引起湿热疲劳。特别地,膜中的水量在瞬变期间显着变化,并确定离子电导率和膜的结构性质。在这项工作中,我们提出了三维时间相关的仿真和PEM燃料电池中运输的分析。使用气体通道中不可压缩的Navier-Stokes方程,通道中的Maxwell-Stefan方程和气体扩散层对阳极和阴极蛇形流动通道,阳极和阴极气体扩散层的U型截面以及夹在它们之间的膜进行模拟,膜中水传输的对流扩散型方程式以及膜中离子电流和气体扩散电极中电流的欧姆定律。通过模拟获得了对负载,压力 ud和阴极相对湿度阶跃变化的瞬态响应,这些响应是通过第三方有限元软件包COMSOL进行的。

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  • 年度 2007
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  • 正文语种 {"code":"en","name":"English","id":9}
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