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Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3-bromooxindoles with α-arylated malonate esters

机译：双（膦）铜催化剂对3-溴氧吲哚酸酯的非对称烷基化的二苯（膦）铜催化剂的立体化学评价

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摘要

An improved method for the asymmetric alkylation of 3-bromooxindoles with α-arylated malonate esters is described. The asymmetric alkylation demonstrated was achieved up to 70% ee utilizing a copper(II) bis(phosphine) complex.

机译：描述了一种用α-芳基丙二酸酯对3-溴恶吲哚进行不对称烷基化的改进方法。利用铜（II）双（膦）配合物，证明不对称烷基化达到了70％ee。

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Chung Whan Lee; Seo-Jung Han; Scott C. Virgil; Brian M. Stoltz;
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年度 2015
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1. Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3-bromooxindoles with alpha-arylated malonate esters [J] . Lee Chung Whan, Han Seo-Jung, Virgil Scott C., Tetrahedron . 2015,第22期

机译：双（膦）铜催化剂对3-溴代吲哚与α-芳基丙二酸酯的不对称烷基化的立体化学评估
2. Substrate and catalyst screening in platinum-catalyzed asymmetric alkylation of bis(secondary) phosphines. Synthesis of an enantiomerically pure C-2-symmetric diphosphine [J] . Anderson BJ, Glueck DS, DiPasquale AG, Organometallics . 2008,第19期

机译：铂催化双（仲）膦的不对称烷基化反应中的底物和催化剂筛选。对映体纯的C-2-对称二膦的合成
3. Mechanistic studies on the asymmetric alkylation of amino ester enolates using a copper(II)salen catalyst [J] . Donatella Band, Yuri N.Belokon, Wen-Lan Fu, Chemical Communications . 2005,第21期

机译：铜（II）salen催化剂催化氨基酯烯醇盐不对称烷基化的机理研究
4. Asymmetric Conjugate Addition of Arylbismuths or -borons to Enones Catalyzed by Cationic Palladium(II)-Phosphine Catalysts [C] . Takashi Nishikata, Yasunori Yamamoto, Norio Miyaura Symposium on Organometallic Chemistry . 2004

机译：不对称缀合物加入芳基肌动酮或 - 硼酮以阳离子钯（II） - 膦催化剂催化的蜗杆
5. Application of chiral bis(phosphine) monosulfide ligands to palladium-catalyzed asymmetric allylic alkylation. [D] . Wilt, Jeremy Clinton. 2005

机译：手性双（膦）单硫化物配体在钯催化的不对称烯丙基烷基化反应中的应用。
6. Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3-bromooxindoles with α-arylated malonate esters [O] . Chung Whan Lee, Seo-Jung Han, Scott C. Virgil, -1

机译：双（膦）铜催化剂对3-溴代吲哚与α-芳基丙二酸酯不对称烷基化的立体化学评估
7. Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3-bromooxindoles with α-arylated malonate esters [O] . Lee Chung Whan, Han Seo-Jung, Virgil Scott C., 2015

机译：双（膦）铜催化剂对3-溴代吲哚与α-芳基丙二酸酯不对称烷基化的立体化学评估

Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3-bromooxindoles with α-arylated malonate esters

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