首页> 外文OA文献 >REDUCTIVE CLEAVAGE WITH METAL IN LIQUID AMMONIA: I. THE SELECTIVE CLEAVAGE OF THE BENZYLTHIO C—S BOND VERSUS THE BENZYLIDENEDIOXY C—O BOND IN METHYL S-BENZYL-4,6-O-BENZYLIDENE-2-THIO-α-D-ALTROPYRANOSIDES; THE INFLUENCE OF THE COSOLVENT 1,2-DIMETHOXYETHANE ON THE COURSE OF THE REACTION

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REDUCTIVE CLEAVAGE WITH METAL IN LIQUID AMMONIA: I. THE SELECTIVE CLEAVAGE OF THE BENZYLTHIO C—S BOND VERSUS THE BENZYLIDENEDIOXY C—O BOND IN METHYL S-BENZYL-4,6-O-BENZYLIDENE-2-THIO-α-D-ALTROPYRANOSIDES; THE INFLUENCE OF THE COSOLVENT 1,2-DIMETHOXYETHANE ON THE COURSE OF THE REACTION

机译：用液氨中的金属还原切割：I。苄硫基C-S键的选择性切割与甲基S-苄基-4,6-O-苄基二甲基-2-甲基 - 滴水吡喃糖苷中的苄基二氧基C-O键; Cosolvent 1,2-二甲氧基乙烷对反应过程的影响

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U. G. Nayak; R. K. Brown;
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年度 1966
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1. SYNTHESIS OF ASYMMETRICAL ARYL-TIN COMPOUNDS BY CLEAVAGE OF ALKYL-TIN BONDS WITH SODIUM METAL IN LIQUID AMMONIA FOLLOWED BY S(RN)1 REACTIONS WITH CHLOROARENES [J] . Yammal CC., Rossi RA., Podesta JC. Journal of Organometallic Chemistry . 1996,第1期

机译：S（RN）1与氯代芳烃反应后在液氨中裂解金属锡与烷基锡键合反应合成不对称芳基锡化合物
2. Alkyne-phosphinoalkyne copuling reactions onmixed-metal tungsten-cobalt centres; P-C(alkyne) bond cleavage versus P-C(alkyne) bond preservation [J] . John E. Davies, MartinJ. Mays, Paul R. Raithby, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2001,第8期

机译：混合金属钨钴中心上的炔烃-膦炔烃偶联反应; P-C（炔）键裂解与P-C（炔）键保留
3. Metal ion-mediated selective activations of C-H and C-CI bonds. Direct aromatic thiolation reactions via C-S bond cleavage of dithioacids [J] . BIDYUT KUMAR SANTRA, GOUTAM KUMAR LAHIRI Proceedings of the Indian Academy of Sciences . 1999,第3期

机译：金属离子介导的C-H和C-CI键的选择性活化。通过二硫代酸的C-S键裂解直接进行芳族硫醇化反应
4. Carbon-sulfur bond formation/cleavage reactions of metal-stabilized thiyl radicals by electrochemical and chemical methods [D] . Sampson, Kagna Ouch 2012

机译：金属稳定的噻吩基的碳硫键形成/裂解反应的电化学和化学方法
5. Applications of Bis(1-R-imidazol-2-yl)disulfides and Diselenides as Ligands for Main Group and Transition Metals: κ2-NN Coordination S-S Bond Cleavage and S-S/E-E (E = S Se) Bond Metathesis Reactions [O] . Joshua S. Figueroa, Kevin Yurkerwich, Jonathan Melnick, -1

机译：双（1-R-咪唑-2-基）二硫化物和二硒化物作为主族和过渡金属的配体的应用：κ2-NN配位SS键断裂和SS / EE（E = SSe）键复分解反应
6. Applications of Bis(1-R-imidazol-2-yl)disulfides and Diselenides as Ligands for Main-Group and Transition Metals: κ2-(N,N) Coordination, S−S Bond Cleavage, and S−S/E−E (E = S, Se) Bond Metathesis Reactions [O] . Joshua S. Figueroa, Kevin Yurkerwich, Jonathan Melnick, 2007

机译：双（1-R-咪唑-2-基）二硫化物和二烯烃作为主基团和过渡金属配体的应用：κ2-（n，n）配位，s-s键裂解和s-s / E-e （e = s，se）键复分解反应
7. Reactions of Metal-Metal Multiple Bonds. 8. Forming Mo-Mo Quadruple Bonds by Reductive Elimination (Alkyl Group Disproportionation) in the Reactions of 1,2-Mo2R2(NMe2)4 Compounds (M triple bond M) with Carbon Dioxide and 1,3-Diary [R] . Chisholm, M. H., Folting, K., Haitko, D. A., 1981

机译：金属 - 金属多重键的反应。 8.通过还原消除（烷基基团歧化）在1,2-mo2R2（Nme2）4化合物（m三键m）与二氧化碳和1,3-日本的反应中形成mo-mo四键

REDUCTIVE CLEAVAGE WITH METAL IN LIQUID AMMONIA: I. THE SELECTIVE CLEAVAGE OF THE BENZYLTHIO C—S BOND VERSUS THE BENZYLIDENEDIOXY C—O BOND IN METHYL S-BENZYL-4,6-O-BENZYLIDENE-2-THIO-α-D-ALTROPYRANOSIDES; THE INFLUENCE OF THE COSOLVENT 1,2-DIMETHOXYETHANE ON THE COURSE OF THE REACTION

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