Determination of Polycyclic Aromatic Hydrocarbons by Gas Chromatography/Mass Spectrometry and Method Development in Supercritical Fluid Chromatography

摘要

The occurrence of polycyclic aromatic hydrocarbons (PAHs) in different Finnish sources was studied by gas chromatography/mass spectrometry (GC/MS). The levels of some 25 PAHs were determined in ambient air, environmental tobacco smoke and food samples. The reliability of the results was estimated and the total PAH intake of the Finnish population was calculated on the basis of the measured and literature data. Smoking was by far the most important contributor to the intake of PAHs by breathing. Ambient air and environmental tobacco smoke (ETS) had a substantial impact, too. Smoked and grilled food contain high levels of PAHs, but adjusting for total food consumption, cereals were the major contributor to the total oral intake. The suitability of supercritical fluid chromatography (SFC) for PAH determination was evaluated, with particular attention to sample introduction techniques (split, delayed split and direct injection). The parameters contributing to the performance were evaluated and the performance was measured quantitatively. The use of supercritical fluid as an extraction eluent was evaluated on the basis of the studies on injection and incorporated into the analytical scheme. (Copyright (c) Valtion teknillinen tutkimuskeskus(VTT)1990.)