首页> 美国政府科技报告 >Crystal and molecular structure of azatranes: Azavanadatran (Z=t-Bu), monoazasilatrane (Z=H), azalithatrane (Z=Clo*4*), azaphosphatrane (Z=Me), azagermatrane (Z=t-Bu) and Azaalumatran (Z=nothing)

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Crystal and molecular structure of azatranes: Azavanadatran (Z=t-Bu), monoazasilatrane (Z=H), azalithatrane (Z=Clo4), azaphosphatrane (Z=Me), azagermatrane (Z=t-Bu) and Azaalumatran (Z=nothing)

机译：氮杂吲哚的晶体和分子结构：azavanadatran（Z = t-Bu），单氮杂硅烷（Z = H），azalithatranerane（Z = Clo * 4 *），azaphosphatrane（Z = me），azagermatrane（Z = t-Bu）和azaalumatran （Z =无）

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The crystal and molecular structures of azatranes have been extensively studied for a variety of M atoms. The crystal and molecular structures of six similar cage compounds: (t-Bu)NV(MeNCH(sub 2)CH(sub 2))(sub 3)N, HSi(OCH(sub 2)CH(sub 2))(sub 2)(HNCH(sub 2)CH(sub 2))N, O(sub 4)ClLi(HNCH(sub 2)SH(sub 2))(sub 3)N, MeP(Me(sub 3)NCH(sub 2)CH(sub 2))(sub 3)N, t-BuGe(HNCH(sub 2)CH(sub 2))(sub 3)N, and Al(Me(sub 3)SiNCH(sub 2)CH(sub 2))(sub 3)N were determined by the use of three-dimensional, single crystal x-ray diffraction.

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Wang, T.;
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年度 1996
页码 1-59
总页数 59
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Germanium Compounds ; Lithium Compounds ; Molecular Crystals ; Organic Compounds ; Phosphorus Compounds ; Silicon Compounds ; Vanadium Compounds ; Crystal Lattices ; Crystal Structure ; Crystallography ; Hexagonal Lattices ; Monoclinic Lattices ; Trigonal Lattices ; X-Ray Diffraction;

机译：锗化合物;锂化合物;分子晶体;有机化合物;磷化合物;硅化合物;钒化合物;晶体晶体;晶体结构;晶体学;六角晶格;单斜晶格;三角晶格; X射线衍射;

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机译：镓氮化合物是通过二氢萘与热消除反应制得的。 [[PhMe2CCH2）（2）GaNH（t-Bu）]（2）和[（H4C6）Me2CCH2] Ga [NH（t-Bu）]（2）Ga（CH2CMe2Ph）（2）的晶体和分子结构
2. Formationand crystal structures of a monomer-dimer pair of mono(cyclopentadienyl)calcium complexes, [C_5(t-Bu)_3H_2]_2CaI(THF)_2 and {[C_5(t-Bu)_3H_2]_2CaI(THF)}_2 [J] . Melanie J. Harvey, Timothy P. Hanusa, Victor G. Young Journal of Organometallic Chemistry . 2001,第1a2期

机译：单（环戊二烯基）钙配合物[C_5（t-Bu）_3H_2] _2CaI（THF）_2和{[C_5（t-Bu）_3H_2] _2CaI（THF）} _ 2的单体-二聚体对的形成和晶体结构
3. Formation and crystal structures of a monomer-dimer pair of mono(cyclopentadienyl) calcium complexes, [C-5(t-Bu)(3)H-2](2)CaI(THF)(2) and {[C-5(t-Bu)(3)H-2](2)CaI(THF)}(2) [J] . Harvey MJ., Young VG., Hanusa TP. Journal of Organometallic Chemistry . 2001,第1a2期

机译：单（环戊二烯基）钙配合物[C-5（t-Bu）（3）H-2]（2）CaI（THF）（2）和{[C-5 （t-Bu）（3）H-2]（2）CaI（THF）}（2）
4. SYNTHESES, MOLECULAR STRUCTURES AND EXPLOSIVE PROPERTIES OF M(CHZ)_3(ClO_4)_2(M = Cd,Ni,Mn) [C] . Lu Chunhua, Zhang Tonglai, Cai Ruijiao 3rd International Autumn Seminar on Propellants, Explosives and Pyrotechnics Oct 5-8, 1999 Chengdu, China . 1999

机译：M（CHZ）_3（ClO_4）_2（M = Cd，Ni，Mn）的合成，分子结构和爆炸性质
5. Mechanisms of electron transfer and hydrogen activation in selected triruthenium clusters with multiple bridging ligands. Part I. The attenuation of radical reactivity in triruthenium trihydrido(alkylidyne) clusters. Electrochemistry and kinetics of decomposition of the 47-electron cluster radical, via a disproportionation path. Part II. The activation of molecular hydrogen at transition metal centers via kinetics and mechanism of reversible oxidative addition of hydrogen across the metal-metal bond of (mu-hydrogen)(2)Ruthenium(3)(Carbon monoxide)(8)(mu-phosphorus(t-BU)(2))(2). [D] . Bierdeman, David John. 2000

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6. Neutral and reduced Roussin’s red salt ester Fe2(μ-RS)2(NO)4 (R = n-Pr t-Bu 6-methyl-2-pyridyl and 46-dimethyl-2-pyrimidyl): synthesis X-ray crystal structures spectroscopic electrochemical and density functional theoretical investigations [O] . Rongming Wang, Miguel A. Camacho-Fernandez, Wei Xu, -1

机译：中性和还原的鲁辛红盐酯Fe2（μ-RS）2（NO）4（R = n-Prt-Bu6-甲基-2-吡啶基和46-二甲基-2-嘧啶基）：合成X射线晶体结构光谱电化学和密度泛函理论研究
7. The crystal and molecular structure of azatranes: Azavanadatran (Z=t-Bu), monoazasilatrane (Z=H), azalithatrane (Z=Clo*4*), azaphosphatrane (Z=Me), azagermatrane (Z=t-Bu) and Azaalumatran (Z=nothing) [O] . Wang, T. 1996

机译：氮杂吲哚的晶体和分子结构：氮杂萘烷（Z = t-Bu），单氮杂硅烷（Z = H），氮杂胞嘧啶（Z = Clo * 4 *），氮杂磷川（Z = me），azagermatrane（Z = t-Bu）和azaalumatran（Z =无）
8. Crystal and molecular structure of azatranes: Azavanadatran (Z=t-Bu), monoazasilatrane (Z=H), azalithatrane (Z=Clo*4*), azaphosphatrane (Z=Me), azagermatrane (Z=t-Bu) and Azaalumatran (Z=nothing) [R] . Wang, T. 1996

机译：氮杂吲哚的晶体和分子结构：azavanadatran（Z = t-Bu），单氮杂硅烷（Z = H），azalithatranerane（Z = Clo * 4 *），azaphosphatrane（Z = me），azagermatrane（Z = t-Bu）和azaalumatran （Z =无）

Crystal and molecular structure of azatranes: Azavanadatran (Z=t-Bu), monoazasilatrane (Z=H), azalithatrane (Z=Clo*4*), azaphosphatrane (Z=Me), azagermatrane (Z=t-Bu) and Azaalumatran (Z=nothing)

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Crystal and molecular structure of azatranes: Azavanadatran (Z=t-Bu), monoazasilatrane (Z=H), azalithatrane (Z=Clo4), azaphosphatrane (Z=Me), azagermatrane (Z=t-Bu) and Azaalumatran (Z=nothing)