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Photochemical Reactivation of the Hydrogenation Catalyst RhHCO(PPh sub 3 ) sub 3 : Preliminary Communication

机译：氢化催化剂RhHCO（pph sub 3）子3的光化学再活化：初步通信

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The activity of the hydrogenation catalyst RhHCO(PPh sub 3 ) sub 3 decreases with time. The catalyst can be reactivated under weak uv-irradiation. (ERA citation 05:019193)

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Strohmeier, W.; Csontos, G.;
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年度 1974
页码 p.1-6
总页数 6
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Hydrogenation; Rhodium complexes; Catalysts; Catalytic effects; Organometallic compounds; Photochemical reactions; Radiation effects; Ultraviolet radiation;

机译：氢化;铑配合物;催化剂;催化效果;有机金属化合物;光化学反应;辐射效应;紫外线辐射;

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1. Ruthenium dihydride RuH2(PPh3)(2)((R,R)-cyclohexyldiamine) and ruthenium monohydride RuHCl(PPh3)(2)((R,R)-cyclohexyldiamine): Active catalyst and catalyst precursor for the hydrogenation of ketones and imines [J] . Abdur-Rashid K., Morris RH., Lough AJ. Organometallics . 2000,第14期

机译：二氢化钌RuH2（PPh3）（2）（（R，R）-环己基二胺）和一氢化钌RuHCl（PPh3）（2）（（R，R）-环己基二胺）：酮和亚胺氢化的活性催化剂和催化剂前体
2. PPh_3-Substituted[2,5-Ph_2-3,4-Tol_2(eta~5-C_4COH)]Ru(CO)(PPh_3)H Exhibits Slower Stoichiometric Reduction,Faster Catalytic Hydrogenation,and Higher Chemoselectivity for Hydrogenation of Aldehydes over Ketones Than the Dicarbonyl Shvo Catalyst [J] . Charles P. Casey, Neil A. Strotman, Sharon E. Beetner, Organometallics . 2006,第5期

机译：PPh_3-取代的[2,5-Ph_2-3,4-Tol_2（eta〜5-C_4COH）] Ru（CO）（PPh_3）H具有较慢的化学计量还原，较快的催化加氢和较高的对醛在醛上进行加氢的化学选择性二羰基Shvo催化剂
3. The PPh_3-Substituted Hydroxycyclopentadienyl Ruthenium Hydride [2,5-Ph_2-3,4-Tol_2(eta~5-C_4COH)]Ru(CO)(PPh_3)H Is a More Efficient Catalyst for Hydrogenation of Aldehydes [J] . Charles P. Casey, Neil A. Strotman, Sharon E. Beetner, Organometallics . 2006,第5期

机译：PPh_3-取代的羟基环戊二烯基氢化钌[2,5-Ph_2-3,4-Tol_2（eta〜5-C_4COH）] Ru（CO）（PPh_3）H是一种更高效的醛加氢催化剂
4. Preliminary Study of Pd/CeO2 Derived from Cerium Complexes as Solid Support Catalysts for Hydrogenation Reaction in a Micro-reactor [C] . Worawat Wattanathana, Arunee Lakkham, Attaphon Kaewvilai Eco-Energy and Materials Science and Engineering Symposium . 2011

机译：衍生自铈配合物的Pd / CeO2的初步研究作为微反应器中的氢化反应的固体载体催化剂
5. I. Stereochemistry of cyclopropane formation involving group (IV) organometallic complexes. II. Slower stoichiometric and faster catalytic reduction of aldehydes by the PPh(3) substituted hydroxycyclopentadienyl ruthenium hydride [2,5-Ph(2)-3,4-Tol(2)(eta(5)-C(4)COH)]Ru(CO)(PPh(3))H: A highly chemoselective catalyst for hydrogenation of aldehydes over ketones. [D] . Strotman, Neil Adham. 2005

机译：I.涉及（IV）族有机金属配合物的环丙烷形成的立体化学。二。由PPh（3）取代的羟基环戊二烯基氢化钌[2,5-Ph（2）-3,4-Tol（2）（eta（5）-C（4）COH）] Ru的化学计量较慢和较快的醛催化还原（CO）（PPh（3））H：一种高度化学选择性的催化剂，用于醛在酮上的氢化。
6. Bioinspired Hydrogenase Models: The Mixed-ValenceTriiron Complex Fe3(CO)7(μ-edt)2 and Phosphine Derivatives Fe3(CO)7–x(PPh3)x(μ-edt)2 (x = 1 2) and Fe3(CO)5(κ2-diphosphine)(μ-edt)2 as Proton Reduction Catalysts [O] . Ahibur Rahaman, Shishir Ghosh, David G. Unwin, -1

机译：生物启发的氢化酶模型：混合价三铁配合物Fe3（CO）7（μ-edt）2和膦衍生物Fe3（CO）7–x（PPh3）x（μ-edt）2（x = 12）和Fe3（CO） 5（κ2-二膦）（μ-edt）2作为质子还原催化剂
7. PPh3-Substituted 2, 5-Ph2-3, 4-Tol2(h5-C4COH)Ru(CO)(PPh3)H Exhibits Slower Stoichiometric Reduction, Faster Catalytic Hydrogenation, and Higher Chemoselectivity for Hydrogenation of Aldehydes over Ketones Than the Dicarbonyl Shvo Catalyst [O] . -1

机译：PPH3取代的2,5-PH2-3，4-T12（H5-C4COH） Ru（CO）（PPH3）H表现出较慢的化学计量还原，更快的催化氢化，更高的化学选择性，用于丙酮的醛氢化而不是二羰基Shvo Catalyst.
8. Photochemical Activation of the Hydrogenation Catalyst IrCl(CO) (PPh sub 3 ) sub 2 [R] . Strohmeier, W., Csontos, G. 1974

机译：氢化催化剂IrCl（CO）（pph sub 3）sub 2的光化学活化

Photochemical Reactivation of the Hydrogenation Catalyst RhHCO(PPh sub 3 ) sub 3 : Preliminary Communication

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