Heterogeneous Chemistry of Importance in Decisions Concerning the Environmental Impact of Energy Production and the Siting of New Energy Sources. Progress Report, March 1, 1979-February 29, 1980

摘要

Research progress in the following areas is reported: (1) the formation, stability, and structure of ion-clusters both by high pressure mass spectrometric experiments and approximate molecular orbital quantum mechanical calculations; (2) the exchange of energy and angular momentum during ion-molecule association reactions using computer dynamics calculations; (3) related experimental and theoretical studies of nucleation and solvation phenomena; (4) laser photophysics of ion clusters including measurement of cross sections for photodissociation, fluorescence, and energy exchange by pulsed infrared techniques; (5) the growth, stability, and structure of weakly-bound van der Waals and charge-transfer complexes employing electric deflection techniques and taking advantage of the first-order Stark effect; and (6) the multiphoton ionization of metal atom clusters to probe the transition from the isolated atomic to the condensed metallic state, and to elucidate their electronic states and potential as sites for the catalytic conversion of absorbed pollutants. (ERA citation 05:019308)