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美国政府科技报告
>Crossed Reaction Networks in the Catalytic Hydrodenitrogenation of Synthetic Liquid Fuels. Quarterly Report, February 1, 1983-April 30, 1983 (Effects of Small Quantities of H sub 2 O, H sub 2 S Generated by Adding CS sub 2 ; Sometimes Small Quantities of
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Crossed Reaction Networks in the Catalytic Hydrodenitrogenation of Synthetic Liquid Fuels. Quarterly Report, February 1, 1983-April 30, 1983 (Effects of Small Quantities of H sub 2 O, H sub 2 S Generated by Adding CS sub 2 ; Sometimes Small Quantities of
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机译:合成液体燃料催化加氢脱氮中的交叉反应网络。 1983年2月1日至1983年4月30日的季度报告(通过添加Cs sub 2生成的小量H H 2 O,H sub 2 s的影响;有时小量的
Studies at 375 exp 0 C and 6.9 MPa revealed complex interactions between H sub 2 O and H sub 2 S which significantly affect the rate of overall hydrodenitrogenation. In the absence of H sub 2 S, addition of H sub 2 O (generated in situ from decanol) produces an increase in the overall HDN rate that is rapidly reversible. When H sub 2 S is present, a comparable increase in overall rate is observed upon the addition of H sub 2 O; however, most of this increase is maintained for a long period after the H sub 2 O is removed. A standard resulfiding procedure reduces the catalyst activity to the level it had before addition of water. (ERA citation 08:038347)
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